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卤水中低浓度铷、铯的选择性吸附研究

Study on Selective Adsorption of Low Concentration Rubidium and Cesium in Brine

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卤水中铷铯资源的提取对于我国高新技术产业的发展具有重要意义,但卤水成分复杂,实现铷铯与高浓度杂质离子的分离十分困难.普鲁士蓝(FeHCF)及其类似物具有优良的铷、铯选择性,因此成为主流的铷、铯吸附材料.对比普鲁士蓝及四种类普鲁士蓝吸附剂对高盐卤水中低浓度铷、铯的吸附性能.FeHCF由于吸附效果良好、试剂价格较低而被用于后续试验.随后,探究不同因素对FeHCF吸附行为的影响,在优化条件下,铷和铯的吸附率分别为94.4%和99.4%,饱和吸附容量分别为517.3 mg/L和2.8 mg/L.最后,对吸附前后FeHCF的理化性质进行详细分析,验证了FeHCF对铷的成功选择性吸附.
The extraction of rubidium and cesium from brine resources is of great significance to the development of high-tech industry in China.However,the complex composition of the brine makes it difficult to separate rubidium and cesium from high concentrations of impurity ions.Prussian blue(FeHCF)and its analogs have excellent rubidium and cesium selectivity,so they become the mainstream materials for adsorbing rubidium and cesium.The adsorption properties of Prussian blue(FeHCF)and four kinds of Prussian blue analogs for low concentration rubidium and cesium in high-salt brine were comparatively studied.FeHCF is selected for subsequent experiments because of its excellent adsorption performance and low reagent price.Subsequently,the effects of various factors on the adsorption behavior of FeHCF were investigated.Under optimal conditions,the adsorption efficiencies of rubidium and cesium are 94.4%and 99.4%,respectively,and the saturated adsorption capacities are 517.3 mg/L and 2.8 mg/L,respectively.Finally,the physicochemical properties of FeHCF before and after adsorption were analyzed in detail,which verifies the successful adsorption of rubidium.

Prussian bluerubidiumcesiumbrineselective adsorption

杨慧、马保中、陈永强、王成彦

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北京科技大学 冶金与生态工程学院,北京 100083

普鲁士蓝 卤水 选择性吸附

2025

有色金属(冶炼部分)
北京矿冶研究总院

有色金属(冶炼部分)

北大核心
影响因子:1.344
ISSN:1007-7545
年,卷(期):2025.(2)