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酸法地浸采铀中矿物溶解/沉淀量空间演化的逆向模拟

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地浸采铀过程中沿溶浸液流向不仅铀矿物被溶解,同时伴随有大量其它矿物的溶解,沿溶浸液流向矿物溶解、沉淀(形成)量具有随溶浸液运移距离增长而增高的规律.以巴彦乌拉铀矿C12采区南部抽注单元为研究对象,采用逆向模拟方法探讨了沿溶浸液运移方向,矿物溶解、沉淀(形成)量空间分布特征与规律.结果表明:酸法地浸采铀过程中溶浸液运移至27.10 m时,发生溶解的矿物主要有钙长石(溶解量16.95 g/L)、钠长石(溶解量2.8 g/L)、钾长石(溶解量2.00 g/L)、赤铁矿(溶解量8.74 mg/L)、黄铁矿(溶解量7.72 mg/L);发生沉淀的矿物主要有石膏(沉淀量10.45 g/L),新形成的矿物主要有伊利石(形成量13.65 g/L)、高岭石(形成量3.90 g/L).矿物溶解、沉淀(形成)量具有沿程不断增大的空间演化规律,并在空间上具有一致性,长石发生黏土化蚀变和石膏沉淀是造成酸法地浸采铀中含矿层堵塞的重要机制.
Inverse Modeling of Spatial Evolution of Mineral Dissolution/Precipitation Amounts in Acid In-situ Leaching of Uranium
In the process of in-situ leaching for uranium extraction,not only the uranium minerals dissolve,but also significant of other minerals dissolve along the flow path of leach solution and the amount of mineral dissolution and precipitation(formation)along the flow direction of the leaching solution increases with the extension of the migration distance of the leaching solution.Taking the southern pumping unit of C12 mining area of Bayan-Ula uranium mine as the research object,the spatial distribution characteristics and patterns of mineral dissolution and precipitation(formation)along the transport pathway of leaching solution were discussed by using reverse simulation method.The results show that:When the leachate runoff reaches 27.10 meters in the process of acid leaching uranium,the dissolved minerals mainly include anorthite(16.95 g/L),albite(2.8 g/L),potassium feldspar(2.00 g/L),hematite(8.74 mg/L)and pyrite(7.72 mg/L).The precipitated minerals are mainly gypsum(10.45 g/L),and the newly formed minerals are mainly illite(13.65 g/L)and kaolinite(3.90 g/L).The spatial evolution pattern of mineral dissolution and precipitation demonstrates a consistent increase along the leach solution flow path.Clayification alteration of feldspar and gypsum precipitation are important mechanisms that cause blockage of ore-bearing layer in uranium leaching by acid method.

acid in-situ leaching of uraniumdissolution amountprecipitation(formation)amountinverse modelingspatial evolution

刘雪峰、刘金辉、邢拥国、阳奕汉、王如意、刘勇毅

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东华理工大学 水资源与环境工程学院,南昌 330013

中核铀业有限公司,北京 100013

中核内蒙古矿业有限公司,呼和浩特 010010

酸法地浸采铀 溶解量 沉淀(形成)量 逆向模拟 空间演化

2025

有色金属(冶炼部分)
北京矿冶研究总院

有色金属(冶炼部分)

北大核心
影响因子:1.344
ISSN:1007-7545
年,卷(期):2025.(2)