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废旧磷酸铁锂电池集流体分离与正极材料再生

Separation of Waste Lithium Iron Phosphate Batteries and Regeneration of Positive Electrode Materials

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通过优化 NaOH 碱溶条件高效去除集流体黏结剂,保留完整铝箔;利用固相法再生 LiFePO4.当 NaOH 为 0.8 mol/L、固液比 20 mL/g、40℃反应 10 min,正极材料的分离率达到 99.78%,超声 1 min后铝箔回收率为 76%,解决了碱溶条件下铝箔回收的繁琐问题.球磨转速 500 r、球磨 5h,补充 10%高纯LiFePO4的方式固相再生,再生 LiFePO4的最高放电比容量为新材料的94.75%,60 次循环测试后为初始放电比容量的 88.62%.
By optimizing the NaOH alkaline solution conditions,the collector binder is efficiently removed and the complete aluminum foil is retained;Regenerate LiFePO4 using solid-state method.When NaOH is 0.8 mol/L,the solid-liquid ratio is 20 mL/g,and the reaction is conducted at 40 ℃ for 10 minutes,the separation rate of the positive electrode material reaches 99.78%.After 1 minute of ultrasound treatment,the aluminum foil recovery is 76%,solving the cumbersome problem of aluminum foil recovery under alkaline solution conditions.The ball milling speed is 500 r,the ball milling time is 5 hours,and 10% high-purity LiFePO4 is added for the solid-state regeneration.The highest discharge specific capacity of the regenerated LiFePO4 is 94.75% of the new material,and after 60 cycles of testing,it is 88.62% of the initial discharge specific capacity.

waste lithium iron phosphate batteryalkali solution-ultrasonic methodhigh efficiency separationsolid phase regeneration

陈娟、张承龙、张西华、马恩

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上海第二工业大学上海市逆向物流与供应链协同创新中心,上海 201209

上海第二工业大学资源与环境工程学院,上海 201209

废旧磷酸铁锂电池 碱溶-超声法 高效分离 固相再生

上海市逆向物流与供应链协同创新中心开放基金国家重点研发计划

A30YD230111-02A30YD230111-02

2024

有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
年,卷(期):2024.14(1)
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