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废旧磷酸铁锂电池集流体分离与正极材料再生

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通过优化 NaOH 碱溶条件高效去除集流体黏结剂,保留完整铝箔;利用固相法再生 LiFePO4.当 NaOH 为 0.8 mol/L、固液比 20 mL/g、40℃反应 10 min,正极材料的分离率达到 99.78%,超声 1 min后铝箔回收率为 76%,解决了碱溶条件下铝箔回收的繁琐问题.球磨转速 500 r、球磨 5h,补充 10%高纯LiFePO4的方式固相再生,再生 LiFePO4的最高放电比容量为新材料的94.75%,60 次循环测试后为初始放电比容量的 88.62%.
Separation of Waste Lithium Iron Phosphate Batteries and Regeneration of Positive Electrode Materials
By optimizing the NaOH alkaline solution conditions,the collector binder is efficiently removed and the complete aluminum foil is retained;Regenerate LiFePO4 using solid-state method.When NaOH is 0.8 mol/L,the solid-liquid ratio is 20 mL/g,and the reaction is conducted at 40 ℃ for 10 minutes,the separation rate of the positive electrode material reaches 99.78%.After 1 minute of ultrasound treatment,the aluminum foil recovery is 76%,solving the cumbersome problem of aluminum foil recovery under alkaline solution conditions.The ball milling speed is 500 r,the ball milling time is 5 hours,and 10% high-purity LiFePO4 is added for the solid-state regeneration.The highest discharge specific capacity of the regenerated LiFePO4 is 94.75% of the new material,and after 60 cycles of testing,it is 88.62% of the initial discharge specific capacity.

waste lithium iron phosphate batteryalkali solution-ultrasonic methodhigh efficiency separationsolid phase regeneration

陈娟、张承龙、张西华、马恩

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上海第二工业大学上海市逆向物流与供应链协同创新中心,上海 201209

上海第二工业大学资源与环境工程学院,上海 201209

废旧磷酸铁锂电池 碱溶-超声法 高效分离 固相再生

上海市逆向物流与供应链协同创新中心开放基金国家重点研发计划

A30YD230111-02A30YD230111-02

2024

有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
年,卷(期):2024.14(1)
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