有色金属工程2024,Vol.14Issue(2) :24-31.DOI:10.3969/j.issn.2095-1744.2024.02.004

Bi元素的添加对Al-Cu-Si三元共晶合金双峰结构转变的影响

The Effect of Bi Element Addition on Bimodal Structure Transformation in Al-Cu-Si Ternary Eutectic Alloy

孛海娃 唐玲 王永善
有色金属工程2024,Vol.14Issue(2) :24-31.DOI:10.3969/j.issn.2095-1744.2024.02.004

Bi元素的添加对Al-Cu-Si三元共晶合金双峰结构转变的影响

The Effect of Bi Element Addition on Bimodal Structure Transformation in Al-Cu-Si Ternary Eutectic Alloy

孛海娃 1唐玲 1王永善1
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作者信息

  • 1. 陕西理工大学材料科学与工程学院,陕西汉中 723003
  • 折叠

摘要

为了揭示Bi元素对共晶合金中凝固组织的影响和作用机理,使用重力凝固法制备了 Al-Cu-Si-xBi(x=0%、0.01%、0.03%、0.05%、0.07%)三元共晶合金,分析了不同添加量Bi对Al-Cu-Si三元共晶合金凝固的组织特征、相的生长形态特征及相组成等的影响.结果表明:Al-Cu-Si三元共晶合金具有α-Al/θ-Al2Cu二元共晶和α-Al/θ-Al2Cu/β-Si三元共晶的混合双峰共晶结构.未添加Bi时,α-Al/θ-Al2Cu二元共晶呈现典型的辐射状菊花集群形态,α-Al/θ-Al2Cu/β-Si 三元共晶中的Si相呈现长针状形态,双峰共晶结构较不均匀.随着Bi的添加,α-A1/θ-A12Cu二元共晶呈现均匀细小的短片层结构,Si相变为点针状.双峰共晶结构的层片间距的差值也逐渐缩小,当Bi的添加量为0.05%时,变质效果最好,双峰共晶结构最为均匀细小,合金硬度亦最好.

Abstract

To reveal the influence and mechanism of Bi elements with different amount in eutectic phase on the undercooled eutectic solidification structure,Al-Cu-Si-xBi(x=0%、0.01%、0.03%、0.05%、0.07%)eutectic alloys were prepared via using a gravity solidified method.The effect of Bi on the solidification structure of Al-Cu-Si ternery eutectic alloy was investigated.The results show that the Al-Cu-Si ternary eutectic alloy has α-Al/θ-Al2Cu binary eutectic and α-Al/θ-Al2 Cu/β-Si ternary eutectic.The structure is called a bimodal eutectic structure.When Bi is not added,the α-Al/θ-Al2Cu binary eutectic exhibits a typical radial chrysanthemum cluster morphology,the Si phase in α-Al/θ-Al2 Cu/β-Si ternary eutectic exhibits elongated needle like morphology.The bimodal eutectic structure is relatively inhomogeneous.With the addition of Bi,α-Al/θ-Al2Cu binary eutectic exhibits a uniform and fine short layer structure,and the Si phase in α-Al/θ-Al2Cu/β-Si ternary eutectic exhibits dot needle-like morphology.The difference in interlayer spacing of the bimodal eutectic structure gradually decreases.When the amount of Bi added is 0.05%,the modification effect is the optimal,and the bimodal eutectic structure is the most uniform and fine.alloy hardness is optimal.

关键词

三元共晶/双峰/成分过冷/共晶集群/层间间距

Key words

ternary eutectic/bimodal structure/constitutional supercooling/eutectic cluster/interlayer spacing

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基金项目

陕西省科技厅科研基金(2020JM-599)

出版年

2024
有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
参考文献量20
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