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含钛高炉渣氯化铵活化焙烧工艺优化研究

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针对钒钛磁铁矿高炉炼铁产出的含钛高炉渣,开展了氯化铵活化焙烧技术研究,使用响应曲面法对工艺条件进行优化,探究焙烧温度、保温时间、氯化铵配比等因素对TiO2品位和杂质脱除的影响,并建立活化焙烧过程的二次回归方程模型.根据模型计算,焙烧温度、保温时间、氯化铵配比等因素对TiO2品位和铝脱除率影响显著,根据模型预测,在焙烧温度为469 ℃、保温时间为0.97 h、氯化铵配比为41%时,TiO2品位38.94%、铝脱除率91.43%;通过试验验证,在此条件下,浸出渣TiO2品位38.39%、铝脱除率90.39%,试验值与模型预测值误差范围在1.5%以内,证明该优化模型具有可靠性.
Optimisation of Ammonium Chloride Activated Roasting Process for Titanium-Bearing Blast Furnace Slag
The process conditions of ammonium chloride activation roasting titanium-bearing blast furnace slag were optimized by the response surface method,the effects of roasting temperature,holding time and ammonium chloride ratio on TiO2 grade and aluminum removal rate were explored,and the secondary regression equation of chlorammonia activation roasting process was established.The results show that the roasting temperature has a significant effect on the grade of TiO2 and the removal rate of aluminum,Under the optimal conditions of roasting temperature of 469 ℃,holding time of 0.97 h and ammonium chloride ratio of 41%,the model predicted TiO2 grade of 38.94%and aluminum removal rate of 91.43%,and the experimental TiO2 grade was 38.39%and the aluminum removal rate was 90.39%,which was within 1.41%of the predicted value,indicating that the optimization results of the model were reliable.

titanium-bearing blast furnace slagammonium chlorideactivation roastingresponse surface methodinteraction

谢思源、蒋训雄、蒋伟、汪胜东、张登高、赵峰、孙旭东、韩文赋

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矿冶科技集团有限公司,北京 100160

含钛高炉渣 氯化铵 活化焙烧 响应曲面法 交互作用

矿冶科技集团科研基金项目

02-1944

2024

有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
年,卷(期):2024.14(6)
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