首页|含CO2废气再生高钙废水工艺研究

含CO2废气再生高钙废水工艺研究

扫码查看
采用含CO2废气脱除菱镁矿脱钙产生的氯盐废水中的Ca,"以废治废",协同处理,实现了废水循环利用和废气降碳的目的.结果表明,含CO2废气再生含Ca废水的最佳条件为废气流量与溶液量比0.2((mL气/min)/mL液),废气中CO2含量为33%,沉淀温度为40 ℃,MgO添加量为1.2倍理论量,沉淀时间4 h,搅拌线速率3.3 m/s;钙沉淀率为99.62%,产生的除钙渣中碳酸钙含量为97.35%,可作为工业碳酸钙产品.此外,除钙后液中Ca∶Mg摩尔比降至0.003 3,溶液可以有效循环用于含钙菱镁矿脱钙,社会和经济效益显著.
Study on the Regeneration Process of High Calcium Wastewater by CO2 Waste Gas
In this study,the purpose of waste water recycling and waste gas decarburization was realized by using CO2 waste gas to remove Ca from chlorine salt wastewater,which produced by magnesite decalcification,"using waste to treat waste"and collaborative treatment.The optimal conditions for regenerating Ca-containing waste water were as follows:the ratio of waste gas flow to solution is 0.2((mLgas/min)/mLliquid),CO2 content in waste gas was 33%,precipitation temperature was 40 ℃,MgO addition amount was 1.2 times the theoretical amount,and precipitation time was 4 hours,stirring line speed 3.3 m/s.Under these conditions,the calcium precipitation rate is 99.62%,and the calcium carbonate content in the calcium removal slag is 97.35%,which can be used as industrial calcium carbonate products.In addition,the molar ratio of Ca/Mg in the solution is decreased to 0.003 3 after calcium removal,and the solution can be effectively recycled for the decalcification of calcium-containing magnesite,which has significant social and economic benefits.

calcium-containing wastewatermagnesium oxide decalcificationwaste gas decarburizationcarbon peaking and carbon neutralitymagnesite

阮书锋、王振文、江培海、揭晓武、张永禄

展开 >

矿冶科技集团有限公司,北京 100160

含钙废水 氧化镁脱钙 废气降碳 双碳 菱镁矿

国家重点研发计划项目

2022YFC3900801

2024

有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
年,卷(期):2024.14(9)
  • 12