首页|Cu-Ti合金热塑性变形行为及微观组织

Cu-Ti合金热塑性变形行为及微观组织

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钛青铜凭借出色的力学、弹性和抗应力松弛性能,有望取代环境有害的铍青铜合金,成为下一代高强高弹领域的关键材料.采用Gleeble-1500D热模拟试验机,探究了 Cu-Ti合金在变形温度为600~950 ℃和变形速率为0.01~10 s-1间的热变形行为,得到了 Cu-Ti合金的热变形本构关系和热加工图.通过电子背散射衍射(EBSD)对不同热变形制度下Cu-Ti合金的微观组织演变及织构分布进行讨论.结果表明,Cu-Ti合金的热变形激活能约为396.52 kJ/mol,热压缩变形本构方程与实验结果具有良好的匹配关系.在0.01 s-1的应变速率下,合金应力水平随变形温度的升高逐渐降低.在800~850 C时,细小的再结晶晶粒沿晶界处呈链状分布,并伴随着Copper织构的逐渐减少和Brass织构的增加.随着应变温度的升高和应变速率的增大,Cu-Ti合金的再结晶转变进程显著加快.在变形温度达到900 ℃时,Cube织构的含量逐渐降低,再结晶织构取向与变形晶粒取向基本一致.在常见的沉淀强化型铜合金中,Cu-Ti系合金具有相对较低的热变形激活能,更易发生塑性变形且具有较好的热加工稳定性及稳定的热变形组织.
Thermoplastic Deformation Behavior and Microstructure of Cu-Ti Alloy
Titanium bronze,with its excellent mechanical properties,elasticity,and resistance to stress relaxation,was expected to replace environmentally harmful beryllium bronze alloys and become a key material in the next generation of high-strength and high-elasticity applications.The hot deformation behavior of Cu-Ti alloys at deformation temperatures of 600-950 ℃ and deformation rates with 0.01-10 s-1 was investigated using a Gleeble-1500D thermal simulation tester.The constitutive relationship and hot working map of Cu-Ti alloys were established.Microstructural evolution and texture distribution of Cu-Ti alloys under different hot deformation processing conditions were discussed using Electron Backscatter Diffraction(EBSD)technology.The results show that the activation energy for hot deformation of Cu-Ti alloys is approximately 396.52 kJ/mol and the hot compression deformation constitutive equation agrees well with the experimental results.At a strain rate of 0.01 s-1,the stress decreases with the increas in deformation temperature.Fine recrystallized grains form a chain-like distribution along grain boundaries during the deformation temperature of 800 ℃ to 850 ℃,with a gradual reduction in Copper texture and an increase in Brass texture.Higher deformation temperatures and strain rates significantly accelerate the recrystallization transformation process.At 900℃,the content of Cube texture decreases,and the orientation of the recrystallized texture closely matches that of the deformed grains.Among the typical precipitation-strengthened copper alloys,Cu-Ti alloys have relatively low hot deformation activation energy,making them more susceptible to plastic deformation and offering good thermal processing stability and stable hot deformation microstructure.

Cu-Ti alloythermal activation energythermal processing mapmicrostructure

洪松柏、李学花、于倩、朱云卿、罗毅、汪东亚、刘峰

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宁波兴业鑫泰新型电子材料有限公司,浙江宁波 315336

中国有研科技集团有限公司有色金属材料制备加工国家重点实验室,北京 101400

有研工程技术研究院有限公司,北京 101400

北京有色金属研究总院,北京 100088

宁波兴业盛泰集团有限公司,浙江宁波 315336

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Cu-Ti合金 热变形激活能 热加工图 显微组织

2024

有色金属工程
北京矿冶研究总院

有色金属工程

CSTPCD北大核心
影响因子:0.432
ISSN:2095-1744
年,卷(期):2024.14(11)