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升温温度对CuAlMnNi记忆合金晶粒尺寸及性能的影响

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研究了低温循环热处理工艺中的升温温度对CuAlMnNi记忆合金板材组织及性能的影响.结果表明,随着升温温度的提高,在 550℃退火 30 min的析出相α的体积分数和最大尺寸均先增大后减小,平均尺寸不断增加;后续高温退火的晶粒尺寸先增大后减小,合金试样的超弹性先升高后降低,残余应变先减小后增大,且晶粒尺寸越大,启动相变的临界强度越小.其原因是升温温度影响晶界活动性B与α相的析出,进而改变后续高温退火时的晶粒尺寸;晶粒尺寸的增大会降低晶界对马氏体相变的阻碍,提高合金的变形能力,进而表现出对合金板材超弹性的提高和残余应变的降低.
Effect of Heating Temperature on Grain Size and Properties of CuAlMnNi Memory Alloy
In this paper,the effect of heating temperature on the microstructure and properties of Cu Al Mn Ni memory alloy sheet in the low-temperature cyclic heat treatment process is studied.The results show that with the increase of the heating temperature,the volume fraction and the maximum size of the precipitated phase α in the annealing at 550℃ for 30 min are increased and then decreased,and the average size is increasing.The grain size after the subsequent high-temperature annealing is increased and then decreased,and thus the superelasticity of the alloy specimen is increased and then decreased.On the contrary,the residual strain is decreased and then increased.The larger the grain size is,the smaller the critical strength for initiating the phase transformation.The reason for this is that the heating temperature affects the grain boundary activity B and the precipitation of α phase,which in turn changes the grain size during subsequent high-temperature annealing.The increase in grain size reduces the obstruction of the martensitic phase transformation by the grain boundaries and improves the deformability of the alloy,which results in the increasememt of superelasticity and decrement of residual strain.

CuAlMnNi shape memory alloylow-temperature cyclic heat treatmentabnormal grain growthsuperelasticity

张迪、陈忠家、王杰、刘冰

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合肥工业大学 材料科学与工程学院,安徽 合肥 230009

CuAlMnNi记忆合金 低温循环热处理 晶粒异常长大 超弹性

2024

有色金属加工
中国有色金属工业协会 洛阳有色金属加工设计研究院

有色金属加工

影响因子:0.263
ISSN:1671-6795
年,卷(期):2024.53(3)