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二次铝灰湿法提炼过程氨的回收利用研究

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二次铝灰湿法提炼回收铝资源过程中,活性铝化合物与水反应产生氢气、甲烷、氨气等可燃混合气体,采用冷冻水吸收混合气体中的氨气,降低可燃气体中氨气对燃烧器的腐蚀作用.从氨气吸收塔釜采出部分液体,降温后循环回至吸收塔对混合气体进行吸收,分析不同循环量对混合气体脱氨效果的影响.结果表明,原料气中氨气质量分数为53.09%,循环液流量为 6 kg/m3 原料气时,可燃气体中氨气质量浓度可降到 4.38 mg/L,满足燃烧器进气要求,回收的氨水质量分数为 20.46%,满足HG/T 5353-2018 中工业氨水标准.采用冷冻水回收二次铝灰湿法提炼过程可燃气体中的氨气,降低了可燃气体中有害成分对燃烧器的危害,并回收其中的氨气生产工业氨水,可产生一定的经济效益.
Study on Recovery and Utilization of Ammonia in Wet Extraction Process of Secondary Aluminum Ash
In the process of secondary aluminum ash wet extraction and recovery of aluminum resources,the active aluminum compound reacts with water to produce hydrogen,methane,ammonia and other combustible mixed gases.The ammonia in the mixed gas is absorbed by frozen water to reduce the corrosion effect of the ammonia in the combustible gas on the burner.Part of the liquid is extracted from the ammonia gas absorber kettle,and then recycled back to the absorber to absorb the mixed gas after cooling.The influence of different circulation amount on the deammonification effect of the mixed gas is analyzed.The results show that when the mass fraction of ammonia in raw gas is 53.09%and the flow rate of circulation liquid is 6kg/m3 of raw gas,the mass concentration of ammonia in combustible gas can be reduced to 4.38 mg/L,which meets the requirements of the inlet gas of burilers.The mass fraction of recovered ammonia water is 20.46%,which meets the HG/T 5353-2018 industrial ammonia water standard.The use of chilled water to recover ammonia from the combustible gas in the wet extraction process of secondary aluminum ash can reduce the harm of harmful components in the combustible gas to the burner,and recover the ammonia gas to produce industrial ammonia water,which can produce certain economic benefits.

secondary aluminum dross recoveryammonia-containing gasabsorption columnammonia water

李璟、张井峰、邓国平

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TCL环保科技股份有限公司,广东 惠州 516006

二次铝灰回收 含氨气体 吸收塔 氨水

2024

有色金属加工
中国有色金属工业协会 洛阳有色金属加工设计研究院

有色金属加工

影响因子:0.263
ISSN:1671-6795
年,卷(期):2024.53(6)