首页|喜马拉雅东部库曲锂铍花岗质伟晶岩的稀有金属矿物学研究

喜马拉雅东部库曲锂铍花岗质伟晶岩的稀有金属矿物学研究

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在喜马拉雅造山带已发现普士拉、热曲、吉隆、洛扎等多个岩体中花岗岩-伟晶岩与锂铍等稀有金属成矿作用相关,并有大规模的锂辉石伟晶岩(含细晶岩)产出.喜马拉雅东部的库曲岩体也发现了锂辉石伟晶岩出露,主要侵入到主体白云母花岗岩中.本次研究对库曲岩体中不同类型的花岗质伟晶岩进行了详细的岩相学、矿物学和年代学的研究.根据不同矿物组合和产出位置,将库曲伟晶岩分为四类:广泛分布的伟晶岩Ⅰ,主要包含长石-石英-白云母;岩体西部桑玉村出露伟晶岩Ⅱ(包含钠长石-石英-白云母带和细粒钠长石带)和伟晶岩111(锂辉石-钠长石-石英带);岩体东部出露细晶岩脉.库曲伟晶岩都含不同体积百分比的石榴石和电气石,以及典型的稀有金属矿物如绿柱石、铌铁矿族矿物和少量锡石.独居石和铌铁矿族矿物的U(-Th)-Pb同位素年代学结果显示库曲伟晶岩主要形成于~25Ma,还存在稍晚一期的岩浆活动,细晶岩形成于~14Ma.同时代的伟晶岩Ⅰ、Ⅱ和Ⅲ全岩成分呈现出明显的变化趋势,K2O/Na2O、Zr/Hf和Nb/Ta比值、REE总量和Eu/Eu*呈降低趋势,而稀有金属(Li、Be、Nb、Ta、Rb和Cs)含量逐渐增加.矿物的成分变化趋势更明显,从伟晶岩Ⅰ到Ⅲ中白云母的K/Rb比值和MgO含量明显降低,电气石向更富集Li、石榴子石和铌铁矿族矿物向更富集Mn(在伟晶岩Ⅲ中分别接近锰铝榴石和铌/钽锰矿端元组分)、绿柱石向更富集Li-Cs的方向变化.伟晶岩Ⅲ中锡石含量相对增加,常与锂辉石共生.细晶岩脉的矿物学特征介于伟晶岩Ⅰ和Ⅱ之间.综合上述研究显示库曲伟晶岩是花岗质岩浆分异演化的最终产物,矿物是伟晶岩形成过程和分异程度的有效指示剂,库曲的稀有金属成矿作用显示出Be、Be-Nb-Ta(-Sn)、Li-Be-Nb-Ta-Sn(岩体最边缘)矿化的变化趋势.锂辉石是库曲伟晶岩中主要的原生锂矿物,次生的锂辉石和石英后成合晶可能是在富锂流体中形成的,而不是透锂长石降温过程中形成的,这与库曲伟晶岩侵入到白云母花岗岩的产状相符.
The rare-metal mineralogical study on the Kuqu Li-Be-rich granitic pegmatite from the eastern Himalaya
A few leucogranitic plutons related to lithium and beryllium mineralization including Pusila,Rachu,Gyirong and Lhozhag in the Himalayan orogen have been found with the occurrence of large-scale spodumene pegmatite(aplite included).Recently the spodumene pegmatite was found in the field of the Kuqu pluton in the eastern Himalaya,with various types of rare-metal pegmatites all intruded into the main body muscovite granite.The petrographic characteristics,mineralogy,and geochronology of the Kuqu pegmatites were studied in this paper.Based on the mineral assemblage and the location,the Kuqu pegmatites are classified into four types,namely,the pervasive pegmatite Ⅰ(consisting of feldspar-quartz-muscovite),the pegmatite Ⅱ(consisting of albite-quartz-muscovite zone and fine-grained albite zone),the pegmatite Ⅲ(spodumene-albite-quartz zone)in the western Sangyu village and the aplite dike in the eastern Kuqu pluton.The pegmatites all contain various abundance of garnet and tourmaline,and minor rare-metal minerals such as beryl,columbite-group minerals(CGMs)and cassiterite.The U(-Th)-Pb isotopic results of monazite and CGMs indicate the pegmatite Ⅰ,Ⅱ and Ⅲ formed at~25Ma,the main magmatic activity in the Kuqu pluton,and a late magmatic activity of the aplite occurred at~14Ma.The contemporary pegmatite Ⅰ,Ⅱ,and Ⅲ have the decreased trends of the K2O/Na2O,Zr/Hf and Nb/Ta ratios,the total rare-earth elements(REEs)concentration and Eu/Eu*value,and the increased trends of the rare-metal(Li,Be,Nb,Ta,Rb,and Cs)contents.Moreover,the minerals show the more obvious evolved trends,such as the lowering K/Rb ratio and MgO content in the muscovite,the increasing Li concentration in the tourmaline,the increasing spessartine content in the garnet,the increasing mangancolumbite content in the CGMs(close to the Mn-rich end-member),and the increasing Li-Cs content in the beryl.The cassiterite is commonly intergrown with the spodumene in the pegmatite Ⅲ and its abundance is highest in all the samples.The mineralogical features of the younger aplite fall between those of pegmatite Ⅰand Ⅱ.Accordingly,the Kuqu pegmatites are the final product of the evolution of the magmatic evolution suggested by the effective mineral indicators.The related rare-metal mineralizations vary from the Be-,through Be-Nb-Ta(-Sn),to Li-Be-Nb-Ta-Sn mineralization.Spodumene is the primary Li-rich minerals in the Kuqu pegmatite,while the symplektitic spodumene and quartz are possibly secondary products of the Li-rich fluid and feldspar but not from the decomposition of the petalite during the Kuqu pegmatite intruded into the wall-rock.

Spodumene pegmatiteBerylEvolution degreeMineralogical indicatorsEnd-member mineral

谢磊、王汝成、田恩农、陶湘媛、周威、刘小驰、吴福元

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内生金属矿床成矿机制研究国家重点实验室,南京大学地球科学与工程学院,南京 210023

河北地质大学,河北省岩石矿物材料绿色开发重点实验室,宝石与材料学院,石家庄 050031

中国石化江苏油田分公司勘探开发研究院,扬州 225009

中国科学院地质与地球物理研究所,岩石圈演化国家重点实验室,北京 100029

中国科学院大学地球与行星科学学院,北京 100049

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锂辉石伟晶岩 绿柱石 演化程度 矿物指示剂 端元矿物

国家自然科学基金国家自然科学基金青藏高原综合科学考察研究项目(第二次)中央高校基本科研业务费专项

42222202918552092019QZKK0802020614380173

2024

岩石学报
中国矿物岩石地球化学学会,中国科学院地质地球物理研究所

岩石学报

CSTPCD北大核心
影响因子:2.74
ISSN:1000-0569
年,卷(期):2024.40(2)
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