首页|华北克拉通古元古代石墨矿成因研究进展与问题

华北克拉通古元古代石墨矿成因研究进展与问题

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华北克拉通周缘发育有三条古元古代石墨成矿带,包括东部石墨成矿带(胶-辽-吉造山带)、西部石墨成矿带和南部石墨成矿带.这些石墨矿床占全国储量的74%,是我国晶质石墨矿床的重要产地.本文在广泛收集和分析该地区以往石墨矿床研究成果的基础上,对华北克拉通周缘古元古代石墨矿床的分布规律、成因机制、形成时代,及其对地球早期环境演化的启示进行了系统归纳总结,并对存在的关键问题进行了探讨和展望.华北克拉通东部石墨成矿带从北到南石墨矿体主要产出在吉南地区的集安群、辽东地区的辽河群以及胶北地区的荆山群中;西部石墨成矿带中的石墨矿床主要赋存于乌拉山岩群和集宁群中;南部石墨成矿带中的石墨矿则主要出露于华北克拉通南缘太华岩群中.华北克拉通三条石墨成矿带中的石墨矿床具有一定的相似性,都属于区域变质型石墨矿床,含矿岩石都是变质表壳岩,包括含石墨斜长片麻岩、含石墨长英质片麻岩、含石墨透辉麻粒岩、含石墨大理岩等.石墨形态多以鳞片状为主,石墨碳质主要来源于有机物,局部混合有少量的无机碳.这三条石墨成矿带中的含矿岩石具有相似的沉积时代(2.0~2.2Ga)和变质成矿时代(1.8~1.95Ga).华北克拉通周缘这些古元古代巨量石墨矿床的形成是古元古代生命繁盛的最有力证据,对地球早期环境演化具有重要影响:一方面,有机物的大量埋藏可以导致大气氧含量的升高以及碳酸盐碳同位素正向偏移;另一方面,这些埋藏的有机物在后期俯冲碰撞造山过程中将发生变质脱碳作用,消耗氧气并释放富集轻碳同位素12C的CO2,这一过程可能会导致大气氧含量降低以及碳酸盐碳同位素值负向偏移.然而,古元古代巨量有机物的埋藏以及在后期碰撞造山剥蚀风化过程中对地球早期大气的影响具体有多大,还需要我们更多的地质数据来对其进行定量估算.华北克拉通周缘这些形成于古元古代的石墨矿床记录了有机物从埋藏到变质形成石墨的完整过程,是研究这些问题的理想对象,对于我们理解地球早期环境演化过程具有重要的意义.
A review of study on genesis of Paleoproterozoic graphite deposits in the North China Craton:Progresses and Questions
Three Paleoproterozoic graphite metallogenic belts have been identified within the North China Craton,including the Eastern Graphite Belt(Jiao-Liao-Ji orogenic belt),the Western Graphite Belt,and the Southern Graphite Belt.These graphite deposits account for 74%of the national reserves,and thus they are important sources of crystalline graphite deposits in China.On the basis of extensive collection and analysis of previous research results on graphite deposits in this area,this paper systematically summarizes the distribution,genetic mechanism and formation age of the Paleoproterozoic graphite deposits within the North China Craton,and its implications for the early environmental evolution of the Earth.The key problems are discussed and prospected.In the Eastern Graphite Belt,graphite ore bodies from the north to south are mainly produced in the Ji'an Group in the South Jilin,the Liaohe Group in the East Liaodong and the Jingshan Group in the North Jiaodong Peninsula.In the Western Graphite Belt,graphite deposits are mainly found in the Wulashan Group and the Jining Group.In the Southern Graphite Belt,graphite ore deposits are mainly exposed in the Taihua Group on the southern edge of the North China Craton.The graphite deposits in the three graphite metallogenic belts of the North China Craton have certain similarities,and they all belong to regional metamorphic graphite deposits.The ore-bearing rocks are metamorphic supracrustal rocks,including graphitic plagioclase gneiss,graphitic felsic gneiss,graphitic diopside granulite and graphitic marble.The form of graphite is mainly in the form of flake.Graphite carbon is mainly derived from organic matter,and there is a small amount of inorganic carbon mixed locally.The ore-bearing rocks in these three graphite metallogenic belts have similar sedimentary ages and metamorphic metallogenic ages.The sedimentary ages are roughly 2.0~2.2Ga,and the metamorphic metallogenic ages are about 1.8~1.95 Ga.The formation of these massive graphite deposits in the North China Craton is the most powerful evidence of the flourishing of life in the Paleoproterozoic,which has an important impact on the early environmental evolution of the Earth.On the one hand,the mass burial of organic matter can lead to the increase of atmospheric oxygen content and the positive shift of carbonate carbon isotope.On the other hand,these buried organic matter will undergo metamorphic decarbonization during the late subduction collision orogeny,consuming oxygen and release CO2 enriched with light carbon isotope 12 C,which may reduce atmospheric oxygen content and negatively shift carbonates carbon isotope value.However,the burial of huge amounts of organic matter in the Paleoproterozoic and the impact on the early atmosphere of the Earth in the later process of collision orogeny denudation weathering still need more geological data for quantitative estimation.These Paleoproterozoic graphite deposits formed in the North China Craton recorded the complete process of organic matter from burial to metamorphism to form graphite,which is an ideal object for studying these problems,and is of great significance to our understanding of the early environmental evolution of the Earth.

North China CratonPaleoproterozoicGraphite depositEarly Earth environmentGreat Oxidation event

朱建江、张璐、杨焰海、刘振宇

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中国地质科学院地质研究所,北京 100037

北京高压科学研究中心,北京1000193

河北地质大学河北省战略性关键矿产资源重点实验室,石家庄 050031

河北省战略性关键矿产研究协同创新中心,石家庄 050031

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华北克拉通 古元古代 石墨矿 地球早期环境 大氧化事件

国家自然科学基金项目国家自然科学基金项目国家自然科学基金项目中国地质科学院基本科研业务费

920622144237207642002060JKYQN202318

2024

岩石学报
中国矿物岩石地球化学学会,中国科学院地质地球物理研究所

岩石学报

CSTPCD北大核心
影响因子:2.74
ISSN:1000-0569
年,卷(期):2024.40(10)
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