首页|石灰粉煤灰固化石油污染土的渗透特性及其工程再利用探讨

石灰粉煤灰固化石油污染土的渗透特性及其工程再利用探讨

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固化改性污染土的渗透性是推进污染土工程再利用需关注的指标之一.借助GDS环境土柔性壁渗透测试仪,优选兼具吸附与固化作用的石灰粉煤灰作为固化材料,以围压、渗透压、污染强度为变量参数,以固化前后石油污染土的渗透系数及土中残余含油量为指标,结合X射线衍射和扫描电镜,厘清渗透性演变及污染物迁移扩散规律,并以此探讨固化石油污染土的工程再利用性.研究结果表明:固化产物对石油分子的吸附作用弱化了石油斥水性,增加了渗透的有效通道,固化石油污染土的渗透系数较未固化石油污染的提高了两个数量级;土体干密度增大会增强对石油的吸附截流作用,围压、渗透压及污染水平的增大会增强土颗粒间相互作用,均引起石油污染土及固化石油污染土渗透性降低.固化作用可有效控制渗透作用下石油污染物的迁移扩散,各部位的残余含油量均非常接近于初始含油量,避免了渗透污染风险.结合石灰粉煤灰固化石油污染土力学特性(抗压强度为1 280.10 kPa,抗剪强度为388.88 kPa)、渗透性(渗透系数为4.28×10-6~7.39×10-6cm/s)及迁移控制性(波动率为0.30%~4.90%),石灰粉煤灰固化石油污染土可考虑用于有防渗要求的路基类填筑材料进行工程再利用.
Discussion on permeability characteristics of lime and fly ash solidified oil-contaminated soil and its engineering reuse
The permeability of treated contaminated soil is an important factor to consider when reusing polluted soil in engineering projects.In this study,lime and fly ash were chosen as solidification materials due to their ability to both adsorb and solidify contaminants.The permeability coefficients of petroleum-contaminated soil before and after solidification,as well as the residual petroleum content within the soil,was investigated under varying parameters such as confining pressure,osmotic pressure and contamination intensity.X-ray diffraction and scanning electron microscopy were used to analyze the evolution of permeability and the migration and diffusion patterns of pollutants,providing insights into the engineering reutilization potential of solidified petroleum-contaminated soil.The results showed that the adsorption effect of the solidified product on petroleum molecules weakened the hydrophobicity of the petroleum,increasing the effective permeation pathways in the soil.The permeability coefficient of solidified petroleum-contaminated soil was two orders of magnitude higher compared to non-solidified soil.Both solidified and non-solidified petroleum-contaminated soil exhibited decreased permeability due to the enhanced adsorption and interception capacity of the soil matrix for petroleum,as well as the elevated confining pressure,osmotic pressure,and contamination level,which intensified the interception among soil particles.The solidification process effectively controlled the migration and diffusion of petroleum contaminants under permeation conditions.The residual petroleum content in various locations closely approximated the initial content,reducing the risk of pollution through permeation.Considering the mechanical properties(compressive strength of 1 280.1 kPa,shear strength of 388.88 kPa),permeability(ranging from 4.28×10-6 cm/s to 7.39×10-6 cm/s),and migration control characteristics(fluctuation rate from 0.3%to 4.9%)of lime and fly ash,it can be concluded that lime and fly ash solidified petroleum-contaminated soil can be reused in the construction of subgrade materials that require impermeability.

petroleum-contaminated soilsolidification and stabilizationengineering reutilizationpermeabilitylimefly ash

李敏、李辉、于禾苗、赵博华、齐振霄

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河北工业大学土木与交通学院,天津 300401

河北工业大学河北省土木工程技术创新中心,天津 300401

石油污染土 固化稳定 工程再利用 渗透性 石灰 粉煤灰

国家自然科学基金国家自然科学基金河北省自然科学基金河北省自然科学基金

5227834151978235E2023202087E2018202274

2024

岩土力学
中国科学院武汉岩土力学研究所

岩土力学

CSTPCD北大核心
影响因子:1.614
ISSN:1000-7598
年,卷(期):2024.45(1)
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