湖南理工学院学报(自然科学版)2024,Vol.37Issue(4) :7-14.

新型环氧乙烷/环氧丙烷无规共聚醚磷酸酯的合成及在涂料体系中的应用

Synthesis of a Novel Random Copolyether Phosphate Ester of Epoxyethane/Epoxypropane and Its Application in Coating Systems

杨长安 陈君求 赖华 周从山 陈松
湖南理工学院学报(自然科学版)2024,Vol.37Issue(4) :7-14.

新型环氧乙烷/环氧丙烷无规共聚醚磷酸酯的合成及在涂料体系中的应用

Synthesis of a Novel Random Copolyether Phosphate Ester of Epoxyethane/Epoxypropane and Its Application in Coating Systems

杨长安 1陈君求 2赖华 3周从山 1陈松2
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作者信息

  • 1. 湖南理工学院 化学化工学院,湖南 岳阳 414006
  • 2. 湖南倍特尔新材料有限公司,湖南 岳阳 414027
  • 3. 佛山贝特尔化工有限公司,广东 佛山 528244
  • 折叠

摘要

以甲醇为引发剂,以环氧乙烷和环氧丙烷为原料合成环氧乙烷/环氧丙烷无规共聚醚,然后与五氧化二磷进行酯化反应,合成一种环氧乙烷/环氧丙烷无规共聚醚磷酸酯,并采用核磁共振、红外光谱和凝胶渗透色谱(GPC)对其结构进行了表征.将合成的环氧乙烷/环氧丙烷无规共聚醚磷酸酯应用于溶剂型聚氨酯(PU)、硝基(NC)木器漆体系中,并对其应用性能进行研究.结果表明,所制备漆膜具有优异的展色性、指研色差和储存稳定性.

Abstract

Using methanol as the initiator,an epoxy ethane/epoxy propane random copolyether was synthesized from epoxy ethane and epoxy propane.This copolyether was then subjected to an esterification reaction with phosphorus pentoxide to synthesize an epoxy ethane/epoxy propane random copolyether phosphate ester.The structure of the product was characterized using nuclear magnetic resonance,infrared spectroscopy,and gel permeation chromatography(GPC).The synthesized epoxy ethane/epoxy propane random copolyether phosphate ester was applied to solvent-based polyurethane(PU)and nitro(NC)wood paint systems,and its application performance was studied.The results indicated that the resulting coatings exhibited excellent color development,color difference upon fingerprinting,and storage stability.

关键词

环氧乙烷/环氧丙烷/无规共聚醚/聚醚磷酸酯/木器漆

Key words

ethylene oxide/propylene oxide/random copolyether/copolyether phosphate ester/wood paint systems

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出版年

2024
湖南理工学院学报(自然科学版)
湖南理工学院

湖南理工学院学报(自然科学版)

影响因子:0.259
ISSN:1672-5298
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