Mathematical modeling and simulations of stress mitigation by coating polycrystalline particles in lithium-ion batteries

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外文标题：Mathematical modeling and simulations of stress mitigation by coating polycrystalline particles in lithium-ion batteries

外文摘要：A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCozO2(x≥0.8)(NMC)particles with poly(3,4-ethylenedioxythiophene)(PEDOT).The simulation results show that the coating of primary NMC particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion,and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport,promoting the lithium distribution across the secondary particles more homogeneously.Besides,the lower stiffness,higher ionic conductivity,and larger thickness of the coating layer improve the stress mitigation.This paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMC active particles mitigates stress levels.

外文关键词：

lithium-ion battery(LIB)polycrystalline particlecoatingfinite element simulationNi-rich LiNixMnyCozO2(x≥0.8)(NMC)

作者：

N.IQBAL、J.CHOI、S.F.SHAH、C.LEE、S.LEE

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作者单位：

Department of Mechanical,Robotics,and Energy Engineering,Dongguk University-Seoul,Seoul 04620,Republic of Korea

关键词：

lithium-ion battery(LIB) polycrystalline particle coating finite element simulation Ni-rich LiNixMnyCozO2(x≥0.8)(NMC)

出版年：

2024

DOI：