首页|WC-Ni3Al合金烧结过程WC晶粒生长行为的研究

WC-Ni3Al合金烧结过程WC晶粒生长行为的研究

Growth Behavior of WC Grains in Ni3Al Matrix during Liquid Phase Sintering

扫码查看
本文以WC-36%Ni3Al(文中百分含量如无特殊说明,均为体积分数)合金体系为研究对象,采用传统粉末冶金方法制备出WC-36%Ni3Al和WC-36%Co复合材料,用带能谱分析的扫描电子显微镜观察试样腐蚀后的区域,用EDS检测粘结相的化学组成,采用透射电子显微镜在高倍条件下观察WC形貌特征,研究了2种不同粒度WC在Ni3Al液相基体中的晶粒长大行为.结果表明,在碳饱和条件下烧结后,粗细WC晶粒表面都出现了明显的刻面台阶;细粒度WC晶粒的异常长大得到抑制,这与WC在Ni3Al基体中的低溶解度有关.由于WC晶粒的两个惯习面具有不同的表面能,随着烧结时间的延长,粗粒度WC晶粒平均粒径不断增大且发生取向生长而形成了粗大的WC.
Growth behavior of WC grains with two different sizes in the same liquid matrix has been studied in the WC-36%Ni3Al (volume fraction) system.Traditional powder metallurgy technology was used to manufacture the WC-36%Ni3Al composites and WC-36%Co composites.SEM imaging was performed on etched sections using a scanning electron microscope with an X-ray energy dispersive spectroscopy system.The chemical compositions of binder phase were characterized by energy dispersive spectroscopy.The high-magnification WC morphology was measured using transmission electron microscopy.The samples were sintered under a carbon saturated condition.The present investigation shows that surfaces of coarse WC grains and fine WC grains are strongly micro-faceted and stepped.The growth behavior of fine WC grain is affected by lower solubility of W in Ni3Al matrix and the abnormal growth of WC grains is suppressed.With the increase of sintering time,the average size of the coarse WC grains increases continuously and very large oriented plate-like triangular prismatic WC grains appear,which is attributed to the difference in energy between the two families of prismatic planes.

Grain growthWC-Ni3Algrain shapesintering

张卫兵、夏艳萍、龙坚战、伍文辉

展开 >

硬质合金国家重点实验室,湖南株洲412000

株洲硬质合金集团有限公司,湖南株洲412000

晶粒长大 WC-Ni3Al 晶粒形貌 烧结

国家重点基础研究发展计划(973计划)

2012CB723906

2014

硬质合金
株洲硬质合金集团有限公司

硬质合金

CSTPCD
影响因子:0.754
ISSN:1003-7292
年,卷(期):2014.31(6)
  • 2
  • 2