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高温高压制备WC-3%Co硬质合金及其物理力学性能表征

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高温高压法是合成宝石的有效方法,应用于复合材料的制备,具有超高等静压力和合成时间短这两大优势。本文采用高温高压法制备WC-3%Co硬质合金,利用万能试验机、X射线衍射仪(XRD)、显微硬度计等对试样进行物相组成和力学性能表征。研究了烧结温度对WC-3%Co硬质合金物相和物理力学性能的影响。结果表明:通过高温高压烧结可以确保所制备的硬质合金样品为较为纯净的WC相和Co相;样品的相对密度随着温度的升高而升高,在1 450℃时相对密度可以达到99。3%;随烧结温度的升高,样品的硬度、抗弯强度和断裂韧性均呈现先升高后降低的趋势。当烧结温度为 1 400℃时,制备的WC-Co硬质合金样品具有优异的力学性能,抗弯强度2 230 MPa、硬度22。78 GPa、断裂韧性11。9 MPa·m1/2。
Preparation of WC-3%Co Cemented Carbide at High Temperature and High Pressure and Characterization of its Physical and Mechanical Properties
High temperature and high pressure method,an effective method for synthesizing gems,has the advantages of ultra-high isostatic pressure and short synthesis time in the preparation of composite materials.In this paper,WC-3%Co cemented carbide was prepared at high temperature and high pressure,and the phase composition and mechanical properties of the cemented carbide samples were characterized by using tools including a universal testing machine,an X-ray diffractometer(XRD),and a microhardness tester.The effects of sintering temperature on the phase and physical and mechanical properties of WC-3%Co cemented carbide were investigated.The results show that sintering at high temperature and high pressure can ensure that the prepared cemented carbide samples are pure WC and Co phases;the relative density of the samples increases with the increase of temperature and can reach 99.3%at 1 450℃;the hardness,bending strength and fracture toughness of the samples increase firstly and then decrease with the increase in sintering temperature.WC-Co cemented carbide samples prepared at 1 400 ℃ have excellent mechanical properties,of which bending strength reaches 2 230 MPa,hardness reaches 22.78 GPa and fracture toughness reaches 11.9 MPa·m1/2.

high temperature and high pressuresintering temperatureWC-Cocemented carbidephysical and mechanical property

吴彦红、吴同敬、李虎、吴佳益

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郑州市产品质量检验检测中心,河南郑州,450006

河南省缺陷产品召回中心,河南郑州,450006

河南省计量测试科学研究院,河南郑州,450008

高温高压 烧结温度 WC-Co 硬质合金 物理力学性能

2024

硬质合金
株洲硬质合金集团有限公司

硬质合金

CSTPCD
影响因子:0.754
ISSN:1003-7292
年,卷(期):2024.41(3)