首页|Ar+N2气氛下烧结温度对多组分碳化物添加的Ti(C,N)基金属陶瓷组织和力学性能的影响

Ar+N2气氛下烧结温度对多组分碳化物添加的Ti(C,N)基金属陶瓷组织和力学性能的影响

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采用亚微米级Ti(C,N)和不同种类的超细碳化物,超细Co粉和Ni粉为原料,在Ar+N2 气氛下进行高温低压烧结制备Ti(C,N)基金属陶瓷。采用XRD、SEM研究Ti(C,N)基金属陶瓷的物相组成及微观形貌,利用维氏硬度仪测试、计算合金的维氏硬度及断裂韧性。结果表明:由于碳化物组元种类的增多,烧结温度和传统相比稍高;当烧结温度为1 470℃时,金属陶瓷的微观组织分布均匀,并没有出现明显的晶粒长大,并且物相只有(Ti,M)(C,N)(M=W、Mo、Nb、Ta)固溶相和Co+Ni黏结相,此时材料的硬度和断裂韧性达到最佳匹配(1 730HV10和8。02 MPa·m1/2),通过烧结工艺的优化达到了组织和性能协同调控的目的。
Effects of Sintering Temperature on Microstructure and Mechanical Properties of Ti(C,N)-Based Cermet with Multi-Component Carbides in Ar+N2 Atmosphere
Ti(C,N)-based cermet was prepared by high temperature and low pressure sintering in Ar+N2 atmosphere with submicron Ti(C,N),different kinds of ultrafine carbides,ultrafine Co powder,and Ni powder as raw materials.The phase composition and microstructure of Ti(C,N)-based cermet were studied by X-ray diffraction(XRD)and scanning electron microscope(SEM).The Vickers hardness and fracture toughness of the specimens were calculated by the Vickers hardness tester.The results show that the sintering temperature is slightly higher than the traditional temperature due to the increase in the types of carbide components.When the sintering temperature is 1 470℃,the microstructure distribution of the cermet is uniform,and there is no obvious grain growth.The phase only have(Ti,M)(C,N)(M=W,Mo,Nb,and Ta)solid solution phase and Co+Ni bonding phase.At this time,the hardness and fracture toughness of the specimens match the best(1 730HV10 and 8.02 MPa·m1/2).Through the optimization of the sintering process,the cooperative regulation of microstructure and mechanical properties is realized.

Ti(C,N)-based cermet sintering temperaturemicrostructureVickers hardnessfracture toughness

刘超、姚兴旺、董涛、龙宁华、张卫兵、曾瑞霖、李剑峰

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硬质合金国家重点实验室,湖南 株洲 412000

株洲硬质合金集团有限公司,湖南 株洲 412000

Ti(C,N)基金属陶瓷烧结温度 微观形貌 维氏硬度 断裂韧性

2024

硬质合金
株洲硬质合金集团有限公司

硬质合金

CSTPCD
影响因子:0.754
ISSN:1003-7292
年,卷(期):2024.41(6)