首页|老化效应对涂层表面池沸腾传热性能的影响

老化效应对涂层表面池沸腾传热性能的影响

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压力容器外部冷却(ERVC)是第三代压水堆核电站严重事故缓解策略的关键技术,其表面临界热流密度(CHF)决定了压力容器的完整性。为探究压力容器真实材料SA508钢表面老化对涂层表面CHF特性的影响,开展了 SA508钢光表面和基于SA508钢的TC4钛合金多孔涂层表面在不同老化状态下的沸腾换热特性实验研究。结果表明:SA508钢光表面在水中会快速氧化,随着老化的加深,其CHF呈上升趋势,上升幅度在20%以内;CHF增强的原因在于SA508钢氧化生成了能改善表面润湿性的Fe3 O4磁性微纳米颗粒层。随着氧化的加深,TC4涂层表面由超亲水特性变为疏水特性,基体SA508钢生成的氧化物易堵塞涂层孔隙,CHF呈恶化趋势。
Effect of Aging Effect on Boiling Heat Transfer Performance of Coating Surface
External reactor vessel cooling(ERVC)is a key technology in the severe acci-dent mitigation strategy of third generation pressurized water reactor nuclear power plants,and the critical heat flux(CHF)determines the pressure vessel integrity.Stud-ies on ERVC boiling heat transfer enhanced by coating show that coating surface can sig-nificantly increase CHF,in order to investigate the aging effect of the real material of nuclear reactor pressure vessel SA508 steel surface on CHF characteristics of coating surfaces,experimental studies on boiling heat transfer characteristics of SA 508 steel bare surface and TC4 titanium alloy porous coating surface based on SA 508 steel under different aging conditions were carried out.The substrate of SA508 steel bare surface was made of copper block and 3 mm thick SA508 steel by explosive welding.The TC4 titanium alloy porous coating surface was prepared by spraying particles on the bare sur-face of SA508 steel by supersonic cold gas spray technology.The micro-scale(the diam-eter of particles is 10-50 μm)TC4 titanium alloy particles were accelerated to a high speed of 400-500 m/s by the propulsion from a stream of high-pressure inert gases with a much lower temperature than thermal spraying.Four kinds of aging experiments were carried out on the SA508 steel bare surface and three kinds of aging experiments on the TC4 titanium alloy porous coating surface at the inclination angle of 5°.The results show that the SA508 steel bare surface oxidizes rapidly in water,and the CHF tends to increase with the deepening of aging,within 20%.The scanning electron microscopy and EDS characterization were used to analyze the surface characteristic.The CHF enhancement is due to the generation of Fe3O4 magnetic micro-nano particle layers that improve surface wettability and added the nucleation sites by oxidation of SA 508 steel.Nevertheless,the CHF increase due to oxidation is limited.Compared with the SA508 steel bare surface,the CHF of TC4 coating surface without oxidation increases more than 36.9%.The TC4 coating surface changes from super-hydrophilic to hydrophobic with the deepening of oxidation,the oxide generated by substrate SA 508 steel is easy to clog the coating pores,and the CHF shows a deterioration trend.The application of porous coating technology to enhance the performance of ERVC needs to consider adding oxidation resistance layer between the SA 508 steel substrate and the porous coating surface,and the problem of bonding strength and alternating stress of multilayer coating should be solved.This study helps to deepen the understanding of enhanced heat trans-fer technology for ERVC and lays the foundation for subsequent research.

phase changeheat transfercoatingboiling heat transfercritical heat fluxoxidation

钟达文、廉学新、史昊鹏、韩昱程

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华北电力大学北京市非能动核能安全技术重点实验室,北京 102206

相变 传热 涂层 沸腾换热 临界热流密度 氧化

国家自然科学基金北京市自然科学基金中央高校基本科研业务费

5170606831920352020MS034

2024

原子能科学技术
中国原子能科学研究院

原子能科学技术

CSTPCD北大核心
影响因子:0.372
ISSN:1000-6931
年,卷(期):2024.58(1)
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