超硬材料工程2024,Vol.36Issue(1) :1-8.

PECVD类金刚石涂层的结构及其摩擦腐蚀行为

Structure of PECVD diamond-like carbon coating and its friction corrosion behavior

宋紫炆 肖乐银 肖锦 周思科 张彤彤 马利秋 彭金勇 周升国
超硬材料工程2024,Vol.36Issue(1) :1-8.

PECVD类金刚石涂层的结构及其摩擦腐蚀行为

Structure of PECVD diamond-like carbon coating and its friction corrosion behavior

宋紫炆 1肖乐银 2肖锦 1周思科 1张彤彤 1马利秋 3彭金勇 1周升国1
扫码查看

作者信息

  • 1. 江西理工大学,材料科学与工程学院,江西 赣州 341000
  • 2. 中国有色桂林矿产地质研究院有限公司 国家特种矿物材料工程技术研究中心,广西 桂林 541004
  • 3. 江西理工大学,材料科学与工程学院,江西 赣州 341000;江西理工大学,理学院,江西 赣州 341000
  • 折叠

摘要

采用等离子体增强化学气相沉积技术(PECVD)在316L不锈钢上制备类金刚石(DLC)涂层,系统地研究了所制备类金刚石涂层的表面形貌与结构、不同载荷下的摩擦磨损行为以及NaCl溶液(3.5 wt%)中不同腐蚀时间下的腐蚀行为.研究结果表明:制备的DLC涂层是由sp3 键和sp2 键杂化形成的非晶碳结构,其中sp2-C含量大于sp3-C,具有典型的类金刚石碳特征;DLC涂层结构致密,表面平滑,粗糙度仅为Ra=12.1 nm,能够与316L不锈钢基体结合紧密;DLC涂层的接触角为59.44°,说明涂层表现出一定的润湿性;摩擦磨损测试结果表明DLC涂层具有良好的润滑效果,摩擦系数能低至0.07~0.16,磨损率低至(3.85~6.71)×10-7 mm3/(N·m);电化学测试得到DLC涂层自腐蚀电流密度为6.72×10-6 A·cm-2,阻抗模值高达7.05×104 Ω·cm-2.这些表明PECVD技术制备的DLC涂层具有优异的摩擦学与耐腐蚀性能,能够对316L不锈钢基底材料形成较好的保护性能.

Abstract

Diamond-like carbon(DLC)coating was prepared on 316L stainless steel by plasma enhanced chemical vapor deposition technology.The surface morphology and structure,friction and wear behavior under different loads and corrosion behavior of NaCl solution(3.5wt%)un-der different soaking time were studied.The results show that the prepared DLC coating is an a-morphous carbon structure coating formed by hybridization of sp2 bond and sp3 bond,in which the content of sp2 bond is higher than sp3 bond,and its properties are similar to diamond-like carbon coating.The DLC coating has a dense structure and a smooth surface with a roughness of only Ra=12.1 nm,which can tightly bond with the 316L stainless steel substrate;The contact angle of DLC coating is 59.44°,indicating that the coating exhibits certain wettability.The fric-tion and wear test results show that the DLC coating has good lubrication effect,with a friction coefficient as low as 0.07~0.16 and a wear rate as low as(33.85~6.71)×10-7mm3/N·m.Electrochemical testing showed that the self corrosion current density of DLC coating was 6.72×10-6 A·cm-2,and the impedance modulus was as high as 7.05×104 Ω·cm-2.These indicate that the DLC coating prepared by PECVD technology has excellent tribological and corrosion re-sistance properties,which can form good protective properties for 316L stainless steel substrate materials.

关键词

PECVD/类金刚石/摩擦磨损/电化学腐蚀

Key words

PECVD,diamond-like carbon,friction and wear/electrochemical corrosion

引用本文复制引用

基金项目

江西省教育厅一般项目(GJJ2200827)

国家自然科学基金(52065025)

出版年

2024
超硬材料工程
桂林矿产地质研究院

超硬材料工程

影响因子:0.201
ISSN:1673-1433
参考文献量28
段落导航相关论文