超硬材料工程2024,Vol.36Issue(6) :11-16.

氩气流量对射频CVD法沉积类金刚石碳薄膜的影响

Effect of Argon Gas Flow Rates on the Deposition of Diamond-Like Carbon Thin Films by RF-CVD Technology

汤黎辉 肖长江 任瑛 张群飞 郑皓宇 栗正新
超硬材料工程2024,Vol.36Issue(6) :11-16.

氩气流量对射频CVD法沉积类金刚石碳薄膜的影响

Effect of Argon Gas Flow Rates on the Deposition of Diamond-Like Carbon Thin Films by RF-CVD Technology

汤黎辉 1肖长江 1任瑛 1张群飞 1郑皓宇 1栗正新1
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作者信息

  • 1. 河南工业大学材料科学与工程学院,河南郑州 450001
  • 折叠

摘要

文章采用射频CVD沉积法,以甲烷和氢气为反应物,在硅(111)基底上沉积类金刚石碳薄膜,分析不同氩气流量对类金刚石碳薄膜性能的影响.利用激光拉曼光谱仪对类金刚石碳薄膜的结构特征进行分析,发现在1400~1700 cm-1区间,有一个明显的宽G峰,而在1300~1400 cm-1区间,则出现了一个较弱的肩D峰.研究结果表明,当氩气流量为0 ml/min和10 ml/min时制备的薄膜,符合类金刚石碳薄膜的典型特征;并且随着氩气浓度的增大,可以促进类金刚石碳的生长、抑制杂质的生成以及减少类金刚石碳中的含氢量.当氩气浓度增大到一定值后,则开始抑制类金刚石碳的生长,直至无法长出类金刚石碳膜.当氩气流量为10 ml/min时,获得的类金刚石碳薄膜是最好的.

Abstract

The article used RF-CVD deposition method to deposit diamond-like carbon films on silicon(111)substrate with methane and hydrogen as reactants,and analyzed the effect of different argon gas flow rates on the properties of diamond-like carbon films.U-sing a laser Raman spectrometer to analyze the structural characteristics of diamond-like carbon films,it was found that there is a clear broad G peak in the range of 1400~1700 cm 1,while a weak shoulder D peak appears in the range of 1300~1400 cm-1.It was shown that the films prepared when the argon flow rate was 0 ml/min and 10 ml/min were in accordance with the typical characteristics of diamond-like carbon films;and with the increase of argon concentration,the growth of diamond-like carbon,the inhibition of impurity generation,and the reduction of hydrogen content in diamond-like carbon could be promoted.When the argon concentration increased to a certain value,it began to in-hibit the growth of diamond-like carbon,until the diamond-like carbon could not be grown.The best diamond-like carbon films were obtained when the argon flow rate was 10 ml/min.

关键词

等离子增强化学气相沉积/类金刚石碳膜/拉曼光谱

Key words

Plasma enhanced chemical vapor deposition/Diamond-like carbon films/Ra-man spectra

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出版年

2024
超硬材料工程
桂林矿产地质研究院

超硬材料工程

影响因子:0.201
ISSN:1673-1433
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