超硬材料工程2024,Vol.36Issue(6) :23-28.

铁基结合剂中的金刚石热损伤分析

Thermal damage analysis of diamond in Fe-based binder

谢吉 陈欣
超硬材料工程2024,Vol.36Issue(6) :23-28.

铁基结合剂中的金刚石热损伤分析

Thermal damage analysis of diamond in Fe-based binder

谢吉 1陈欣1
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作者信息

  • 1. 长沙百通新材料科技有限公司,湖南长沙 410600
  • 折叠

摘要

对不同烧结工艺下铁基结合剂中的金刚石热损伤进行分析,发现铁基结合剂胎体会随着烧结温度的提高而加重侵蚀金刚石的外观,损伤金刚石的晶面和棱角;金刚石的静压强度也会在超过一定烧结温度时降低,但在合理的温度范围内,金刚石的冲击强度无明显下降,这表明静压强度能更直观的反应金刚石的外观损伤情况.金刚石镀钛后能够在一定程度上延缓金刚石在铁基胎体中的热损伤,使金刚石被侵蚀的温度提高.金刚石在加压烧结和无压自由烧结的铁基结合剂胎体中的损伤机理不同,加压烧结时其外观的侵蚀优先从理论上最稳定、最难侵蚀的(111)晶面开始;而无压自由烧结时其外观的侵蚀则是从易侵蚀的(100)晶面开始并扩展的,且损伤的程度更深.因而金刚石的热损伤与加压烧结方式有关.

Abstract

The thermal damage of diamond in Fe-based binder under different sintering processes was analyzed.It was found that Fe-based binder would erode the appearance of diamond and damage the crystal surface and edges of diamond with the increase of sinte-ring temperature.The static compressive strength of diamond also decreases when the sintering temperature exceeds a certain level,but the impact strength of diamond does not decrease significantly in a reasonable temperature range,which indicates that the static compressive strength can reflect the appearance damage of diamond more directly.Titani-um plating of diamond can delay the thermal damage of diamond in the Fe-base body to a certain extent and increase the temperature of diamond erosion.The damage mechanism of diamond is different in the Fe-based binder matrix with pressure sintering and free sin-tering.Under pressure sintering,the erosion of diamond appearance starts from the(111)crystal surface which is theoretically the most stable and the most difficult to e-rode.In the case of free sintering without pressure,the erosion of diamond appearance starts and extends from the easily eroded(100)crystal surface,and the damage degree is deeper.Therefore,the thermal damage of diamond is related to the pressure sintering method.

关键词

铁基结合剂/金刚石/热损伤/腐蚀/静压强度

Key words

Fe-based binder/diamond/thermal damage/erosion/static strength

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出版年

2024
超硬材料工程
桂林矿产地质研究院

超硬材料工程

影响因子:0.201
ISSN:1673-1433
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