超硬材料工程2024,Vol.36Issue(6) :45-50.

传压介质叶蜡石的热稳定性研究

Thermal Stability of Pressure Transmission Medium Pyrophylit

王征 张子龙 汪俊博 刘雪坤 李海宁 程学瑞
超硬材料工程2024,Vol.36Issue(6) :45-50.

传压介质叶蜡石的热稳定性研究

Thermal Stability of Pressure Transmission Medium Pyrophylit

王征 1张子龙 1汪俊博 1刘雪坤 1李海宁 1程学瑞1
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作者信息

  • 1. 郑州轻工业大学电子信息学院,河南郑州 450002
  • 折叠

摘要

在高温高压合成金刚石的过程中,叶蜡石作为密封传压介质是必不可少的辅助材料.近年来,超硬材料行业快速发展,对叶蜡石的需求量很大,且叶蜡石开采带来了严重的环境问题.因此,急需对传压介质叶蜡石进行深入研究,构筑叶蜡石结构—物性之间的关联,进而探寻新的密封传压介质材料.采用SEM对北京门头沟叶蜡石原矿与南非叶蜡石原矿进行了形貌表征,并通过EDS对两种矿物进行成分分析.此外,利用XRD和TG分析北京与南非叶蜡石原矿的热稳定性,研究了两种样品在400 ℃、600 ℃、850 ℃和1100 ℃的物相组成,进而获得其高温条件下的结构演化过程.结果表明,北京门头沟叶蜡石和南非叶蜡石在元素成分、矿物组成及其热稳定性等方面均存在差异,也是其传压性能差异的根本原因.

Abstract

Pyrophyllite,as a pressure transmitting medium,is one essential auxiliary ma-terial in the process of high temperature and high pressure diamond synthesis.With the rapid development of super hard material industry,more and more pyrophyllite are nee-ded for diamond synthesis,which induce serious environmental pollution.Therefore,it is urgent to systematically study the pressure transmitting medium for pyrophyllite,con-structing the structure-physical relation and then exploring new pressure transmitting me-dium materials.The thermal stability of Beijing Mentougou pyrophyllite and South Africa pyrophyllite was studied.First,the morphologies of both types pyrophyllite were charac-terized by SEM,and their components were analyzed by EDS technology.In addition,thermal stability was analyzed using XRD and TG.The structural evolution were obtained for two types pyrophyllite during annealing at 400 ℃,600 ℃,850 ℃ and 1100 ℃,respective-ly.The results show that there are differences in elemental composition,mineral compo-sition and thermal stability between Beijing Mentougou pyrophyllite and South Africa py-rophyllite,which may be the fundamental reason for their different pressure transfer per-formance.

关键词

叶蜡石/热稳定性/传压介质/热重分析/金刚石

Key words

pyrophyllite/thermal stability/pressure transfer medium/TG/diamond

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出版年

2024
超硬材料工程
桂林矿产地质研究院

超硬材料工程

影响因子:0.201
ISSN:1673-1433
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