首页|晶粒尺寸对316L不锈钢在模拟人体体液环境中腐蚀行为的影响

晶粒尺寸对316L不锈钢在模拟人体体液环境中腐蚀行为的影响

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为提高医用金属材料的耐腐蚀性能,以一种商用316L不锈钢为研究对象,采用冷轧及退火工艺制备了平均晶粒尺寸为198 nm的超细晶(UFG)、776 nm的亚微米晶(SMG)和1.18 μm的细晶(FG)试样,通过电化学实验测定了不同平均晶粒尺寸试样在模拟人体体液中的动电位极化曲线和电化学阻抗谱.结果表明:腐蚀电位和击穿电位随着平均晶粒尺寸的减小而增大,UFG试样具有较高的腐蚀电位(-0.38 VSCE)和击穿电位(-0.03 VSCE);电容半径随晶粒尺寸的减小而增大,晶粒细化后,316L不锈钢在模拟人体体液环境中的耐腐蚀性能得到提高.其中,退火温度750 ℃条件下保温5 min制备的平均晶粒尺寸为198 nm的超细晶316L不锈钢在模拟人体体液环境中具有最佳的耐腐蚀性能.
Effect of grain size on corrosion behavior of 316L stainless steel in simulated body fluid environment
To improve the corrosion resistance of medical metal materials,a commercial 316L stainless steel was used as the re-search object.Ultrafine-grained(UFG)sample with average grain size of 198 nm,submicron-grained(SMG)sample with average grain size of 776 nm and fine-grained(FG)sample with average grain size of 1.18 μm were prepared by cold rolling and annealing treatment.The potentiodynamic polarization curves and electrochemical impedance spectroscopy of samples with different aver-age grain sizes in simulated body fluid were measured by electrochemical experiments.The results show that the corrosion poten-tial and breakdown potential increase as the average grain size decreases,and UFG samples have higher corrosion potential(-0.38 VSCE)and breakdown potential(-0.03 VSCE).The capacitance radius increases as the grain size decreases,the corro-sion resistance of 316L stainless steel in simulated body fluid is improved by grain refinement.The ultrafine-grained 316L stain-less steel with an average grain size of 198 nm prepared at annealing temperature of 750 ℃ for 5 min has the best corrosion resist-ance in simulated body fluid environment.

316L stainless steelcold rolling and annealing processgrain sizesimulated body fluidcorrosion resistance

陈书航、褚冉星、赵苗苗、吴红艳、杜林秀

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东北大学材料科学与工程学院,辽宁 沈阳 110819

东北大学轧制技术及连轧自动化国家重点实验室,辽宁 沈阳 110819

316L不锈钢 冷轧及退火工艺 晶粒尺寸 模拟人体体液 耐腐蚀性能

国家级大学生创新创业训练计划中央高校基本科研业务费专项

S202210145081N2107013

2024

轧钢
中国钢研科技集团有限公司

轧钢

CSTPCD北大核心
影响因子:0.881
ISSN:1003-9996
年,卷(期):2024.41(1)
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