废旧锂离子电池正极材料回收研究进展
Research Progress on Cathode Material Recycling of Waste Lithium-Ion Batteries
张宝 1梁祯 2张雁南 1孟奇 1董鹏 1张英杰3
作者信息
- 1. 昆明理工大学冶金与能源工程学院 锂离子电池及材料制备技术国家地方联合工程研究中心,云南 昆明 650093
- 2. 昆明理工大学材料科学与工程学院,云南 昆明 650093
- 3. 昆明理工大学冶金与能源工程学院 锂离子电池及材料制备技术国家地方联合工程研究中心,云南 昆明 650093;昆明理工大学材料科学与工程学院,云南 昆明 650093
- 折叠
摘要
随着锂离子电池(lithium-ion batteries,LIBs)在电动汽车、3C电子产品和储能领域的大规模应用和产销量的日益剧增,其退役后带来的金属浪费和环境污染问题也日益突出.有必要大力开发绿色环保、高效低成本的废旧锂离子电池正极材料回收工艺,实现金属资源的周期性利用.回顾了废旧锂离子电池正极材料回收工艺的最新进展.概述了现有的回收工艺,详细介绍了预处理、火法冶金、湿法冶金、生物浸出和直接回收等回收工艺的研究现状.并通过对比分析现有技术存在的问题,综合讨论了各工艺的回收效率、安全性和经济价值.最后,展望了废旧锂离子电池正极材料回收再利用的前景和发展趋势,旨在为直接化、高值化、规模化的废旧锂电池回收再利用研究提供借鉴与参考.
Abstract
With the increasing large-scale application and production as well as the sales of lithium-ion batteries(LIBs)in electric vehicles,3C electronics and energy storage devices,the metal waste and environmental pollution caused by their retirement are also becoming increasingly prominent.It is necessary to vigorously develop a green,environmentally friendly,efficient and low-cost cathode material recycling process for waste lithium-ion batteries to realize the cycle utiliza-tion of non-ferrous metal resources.This paper reviews the latest progress in the material recycling process of cathode ma-terials for the used lithium-ion batteries.The existing recovery processes are summarized.Moreover,the research status of recovery processes such as the pretreatment,pyrometallurgy,hydrometallurgy,biological leaching and direct recovery strategy are detailed illustrated.The problems and the advantages of these technology are compared and analyzed.Further-more,the recovery efficiency,safety and economic value are comprehensively discussed.Finally,the prospect and development trend of the recycling and reuse of cathode ma-terials of used lithium-ion batteries are outlooked,aiming at the direct,high-value and large-scale research on the recy-cling and reuse of used lithium batteries to provide lessons and references.
关键词
废旧锂离子电池/正极材料/预处理工艺/回收工艺/直接回收Key words
waste lithium-ion batteries/cathode mate-rials/pretreatment process/recycling process/direct recovery引用本文复制引用
基金项目
国家自然科学基金项目(52164031)
云南省重大科技项目-昆明理工大学"双一流"科技专项(202202AG050003)
云南省基础研究项目(202101AU070048)
出版年
2024
NETL
NSTL
维普
万方数据