中国材料进展2024,Vol.43Issue(11) :981-987.DOI:10.7502/j.issn.1674-3962.202404016

基于熔体控速滴铸法制备分米级高纯镁单晶的工艺探索

Exploration of Decimeter-Sized High-Purity Magnesium Single Crystal Preparation Based on Melt Controlled-Speed Drop Casting

刘博宇 黄鑫垚 马欣金 郑芮 李峣峰 李玖章 肖鹏 单智伟
中国材料进展2024,Vol.43Issue(11) :981-987.DOI:10.7502/j.issn.1674-3962.202404016

基于熔体控速滴铸法制备分米级高纯镁单晶的工艺探索

Exploration of Decimeter-Sized High-Purity Magnesium Single Crystal Preparation Based on Melt Controlled-Speed Drop Casting

刘博宇 1黄鑫垚 1马欣金 1郑芮 1李峣峰 1李玖章 1肖鹏 1单智伟1
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作者信息

  • 1. 西安交通大学金属材料强度国家重点实验室,陕西西安 710049;西安交通大学陕西省镁基新材料工程研究中心,陕西西安 710049;西安交通大学材料科学与工程学院,陕西西安 710049
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摘要

金属镁具有密排六方晶体结构,其力学性能和物理化学性能具有明显的各向异性.高纯镁单晶是研究镁沿不同晶向的力学性能、腐蚀行为及导电导热等物理化学性能的理想材料.目前,高纯镁单晶常需进口,其价格昂贵,购买手续繁琐,且所能购置的单晶尺寸一般为厘米级甚至更小,难以满足批量化的力学和物理性能测试需求.提出了一种基于熔体控速滴铸法的高纯镁单晶生长方法,并探索了原料纯度、结晶坩埚结构及温度设置等因素对晶体生长的影响规律.应用该方法及装置,成功制备了纯度为99.99%(质量分数)的分米级尺寸高纯镁单晶体.

Abstract

Mag nesium has a hexagonal close-packed(hcp)crystal structure,thus its mechanical and physical/chemical properties exhibit significant anisotropy along variant crystallographic orientations.High-purity magnesium single crystal is an ideal material for studying the mechanical prop-erties,corrosion resistance,electrical and thermal conduc-tivity,and other physical/chemical properties of magnesium along different crystallographic orientations.However,high-purity magnesium single crystals often need to be imported,which are expensive,and the purchase procedures are com-plicated and time-consuming.Moreover,the size of magne-sium single crystal produced by current methods is generally with centimeter or even smaller.The present paper proposes a method for growing high-purity magnesium single crystals based on melt controlled-speed drop casting method.The effects such as raw material purity,crucible configuration,and temperature setting on crystal growth are studied.Using the pro-posed method,decimeter-sized high-purity magnesium single crystals with a purity of 99.99wt%are successfully produced.

关键词

高纯镁/单晶/熔体控速滴铸法/晶体生长

Key words

high-purity magnesium/single crystal/melt controlled-speed drop casting/crystal growth

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出版年

2024
中国材料进展
中国材料研究学会 西北有色金属研究院

中国材料进展

CSTPCDCSCD北大核心
ISSN:1674-3962
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