首页|红外光谱法快速检测生物降解塑料

红外光谱法快速检测生物降解塑料

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随着生物降解塑料的应用,部分商家为降低生物降解塑料成本会添加非降解材质,造成了环境污染,因此快速准确鉴定生物降解塑料成分成重要问题.该文采用红外光谱法测定单一的聚乳酸和聚对苯二甲酸-己二酸丁二醇酯等原材料标准谱图,标记其特征官能团.然后通过溶液共混、熔融共混和原位聚合制备得到不同成分和不同含量的降解材料共混物,测定其红外谱图.通过红外光谱图分析,不同的制备方法对共混物的结构没有影响,无其他副产物的生成,且未发生降解.最后,讨论以高密度聚乙烯为非降解材质、淀粉为降解材质和KH550处理的纳米二氧化硅为无机填料对生物降解的影响,以研究非降解材质、降解材质和无机填料对利用红外光谱快速检测生物降解塑料的干扰.最终形成简单便捷、成本低的红外光谱检测方法.
Rapid detection of biodegradable materials based on infrared spectroscopy
With the application of biodegradable plastics,some businesses will add non-degradable materials to reduce the cost of biodegradable plastics,resulting in environmental pollution.Therefore,rapid and accurate identification of the components of biodegradable plastics has become an important technical issue.In this paper,the standard spectra of raw materials such as polylactic acid and polybutylene terephthalate were determined by infrared spectroscopy,and their characteristic functional groups were marked.Then the degradation material blends with different components and contents were prepared by solution blending,melt blending and in-situ polymerization,and their infrared spectra were measured.Through infrared spectroscopy analysis,it was found that different preparation methods had no effect on the structure of the blend,no other by-products were generated,and no degradation occurred.Finally,the effects of non-degradable materials such as high-density polyethylene,starch and KH550 treated nano-silica as inorganic fillers on biodegradation were discussed to study the interference of non-degradable materials,degradable materials and inorganic fillers on the rapid detection of biodegradable plastics by infrared spectroscopy.Finally,a simple,convenient and low-cost infrared spectrum detection method was formed.

biodegradable plasticsinfrared spectrumrapid detectionblendingqualitative analysis

王晓珂、冯冰涛、马劲松、张信、孙国华、肖军、侯连龙

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河北科技大学材料科学与工程学院河北省柔性重点实验室,河北石家庄 050018

河北敦诚新能源科技有限公司,河北石家庄 050000

生物降解塑料 红外光谱 快速检测 共混 定性分析

河北省重点研发计划项目河北省重点研发计划项目河北省重点研发计划项目河北省重点研发计划项目

20311201D21314401D21374901D19212108D

2024

中国测试
中国测试技术研究院

中国测试

CSTPCD北大核心
影响因子:0.446
ISSN:1674-5124
年,卷(期):2024.50(7)
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