中国地质2024,Vol.51Issue(5) :1601-1616.DOI:10.12029/gc20230309006

全球淡色花岗岩的地球化学特征及其与稀有金属的成矿联系

Geochemical characteristics of global leucogranite and their mineralized relationship with rare metals

赵晨辉 王登红 王成辉 刘善宝 秦锦华 诸泽颖 赵云彪 刘泽 刘金宇 李阳 刘新星
中国地质2024,Vol.51Issue(5) :1601-1616.DOI:10.12029/gc20230309006

全球淡色花岗岩的地球化学特征及其与稀有金属的成矿联系

Geochemical characteristics of global leucogranite and their mineralized relationship with rare metals

赵晨辉 1王登红 1王成辉 1刘善宝 1秦锦华 1诸泽颖 1赵云彪 1刘泽 1刘金宇 1李阳 2刘新星3
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作者信息

  • 1. 中国地质科学院矿产资源研究所,自然资源部成矿作用与资源评价重点实验室,北京 100037
  • 2. 成都理工大学,四川成都 610059
  • 3. 河北地质大学,河北石家庄 050031
  • 折叠

摘要

[研究目的]近年来,淡色花岗岩成为岩石学和稀有金属成矿学研究的热点,但全球淡色花岗岩的时空分布特征尚不明确.本文旨在探讨全球淡色花岗岩的时空分布特征及其成矿专属性,进而指导勘查实践.[研究方法]文章系统梳理了全球 115个淡色花岗岩体 1155组地球化学数据,并结合项目组在南岭、川西、藏南、阿尔泰等地的工作,对数据开展综合分析研究.[研究结果]在成分上,淡色花岗岩的SiO2 含量较全球花岗岩平均值高 1%以上,发生稀有金属矿化的岩体稀土含量极低.在空间上,中西欧海西造山带淡色花岗岩的SiO2 和ALK(Na2O+K2O)含量低于喜马拉雅淡色花岗岩,也低于中国西部淡色花岗岩,而中国西部淡色花岗岩的SiO2 和ALK含量又低于中国东部的淡色花岗岩,中西欧和北美地区的淡色花岗岩富集P2O5;样品中Li、Be、Nb、Ta、Ga、Rb和Sn含量的最高平均值均出现在中西欧地区,W含量最高平均值出现在中国东部.在时间上,新生代淡色花岗岩的SiO2 和ALK含量高于古生代,低于中生代;古生代淡色花岗岩富集P2O5;电气石是新元古代淡色花岗岩的一个重要矿物特征.[结论]成矿的淡色花岗岩一般不含岩浆型石榴子石,A/CNK>1.2,与Sn-W-Nb-Ta成矿有关的淡色花岗岩的 Rb/Sr>1,ΣREE>10×10-6,与 Li-Sn-Nb-Ta-Be成矿有关的淡色花岗岩的 Rb/Sr>1,ΣREE<10×10-6.相比之下,中国东部中生代淡色花岗岩演化程度最高,成矿潜力最好.

Abstract

This paper is the result of mineral exploration engineering.[Objective]Recently,leucogranites have become a hot spot in the study of petrogenesis and rare metal metallogeny.However,the spatiotemporal distribution characteristics of global leucogranite are still unclear.For further prospecting of rare metals in China,it is essentially to clarify the spatiotemporal distribution of leucogranite and the metallogenic specialization between leucogranite and rare metal deposits.[Methods]We collect 1155 geochemical data from 115 leucogranites worldwide,and combine with our recently achievements from the Nanling Region,Western Sichuan,Southern Tibet,and Altai.[Results]In reference to the composition,this study reveals that the content of SiO2 in leucogranite is exceed 1% higher than the global average value of granite,while the REE content of the rocks with rare metal mineralization is extremely low.Spatially,the content of SiO2 and ALK(Na2O+K2O)of leucogranites in the Hercynian orogenic belt in Central and Western Europe are lower than those of the Himalayan leucogranites,as well as those of Western China.Meanwhile,the SiO2 and ALK content of leucogranite in Western China are lower than Eastern China.Both leucogranites in Central and Western Europe and North America are rich in P2O5.The highest values of Li,Be,Nb,Ta,Ga,Rb and Sn in the samples appear in Central and Western Europe,while the highest values of W present in eastern China.Cenozoic SiO2 and ALK content of leucogranite were higher than Paleozoic but lower than Mesozoic.Notablely,Paleozoic leucogranite are enriched in P2O5.Besides,tourmaline is a vital indicator of Neoproterozoic leucogranite.[Conclusions]The mineralized leucogranite are generally lack of magmatic garnet.Those leucogranite with feature of A/CNK>1.2.Rb/Sr>1,ΣREE>10×10-6 are mostly related to Sn-W-Nb-Ta mineralization,while Rb/Sr>1,ΣREE<10×10-6 of leucogranite more akin to Li-Sn-Nb-Ta-Be mineralization.All the data indicate that the Mesozoic leucogranites in Eastern China are the most evolved leucogranites worldwide and the best mineralization potential.

关键词

淡色花岗岩/地球化学/稀有金属/矿产勘查工程/喜马拉雅/海西造山带/中国东部/中国西部

Key words

leucogranite/geochemistry/rare metals/mineral exploration engineering/Himalayas/Hercynian orogenic belt/Eastern China/Western China

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基金项目

国家重点研发计划项目(2021YFC2901900)

国家重点研发计划项目(2021YFC2901905)

中国地质调查项目(DD20221684)

中国地质调查项目(DD20190379)

中国地质调查项目(DD20221695)

国家自然科学青年基金项目(41902037)

出版年

2024
中国地质
中国地质调查局

中国地质

CSTPCDCSCD北大核心
影响因子:2.317
ISSN:1000-3657
参考文献量20
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