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The occurrence of metallic copper and redistribution of copper in the shocked Suizhou L6 chondrite

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The occurrence of metallic copper and redistribution of copper in the shocked Suizhou L6 chondrite
Copper possesses very strong chacophile proper-ties,but under the conditions found in meteorites,its behav-ior is like that of siderophile elements.The Suizhou mete-orite is a highly shocked L6 chondrite.Troilite and taenite are considered the main primary carrier of copper in this meteorite,and the post-shock thermal episode is consid-ered the main reason that elemental Cu migrates from its original host phase and forms metallic grains.The Suizhou meteorite contains a few very thin shock melt veins.The occurrence and behavior of metallic copper in this meteorite were studied by optical microscopic examination,electron microprobe analyses,and high-resolution X-ray elemental intensity mapping.Our results show that metallic copper is abundant in the Suizhou chondritic rock.Metallic copper grains adjacent to small troilite grains inside FeNi metal are the most common occurrence,and those at the FeNi metal-troilite interface are the second most common case.The metallic copper grains occurring at the interface of FeNi metal/troililte and silicate are rather rare.Metallic copper grains are not observed within the Suizhou shock veins,Instead,Cu in elemental form is transferred through shock metamorphism into FeNi metal+troilite intergrowths.Four different occurrence types of Cu in the FeNi metal+troilite intergrowths have been identified:the concentrations of Cu in the FeNi+FeS intergrowths for four occurrence types are rather close,we estimate it might be lower than 1 wt%.

Suizhou chondriteShock veinMetallic copperMetal-troilite intergrowthElemental intensity mapping

Xiande Xie、Xiangping Gu、Yiping Yang

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Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,China

School of Geosciences and Info-Physics,Central South University,Changsha 410083,China

Suizhou chondrite Shock vein Metallic copper Metal-troilite intergrowth Elemental intensity mapping

2024

地球化学学报(英文版)
中国科学院地球化学研究所

地球化学学报(英文版)

EI
影响因子:0.33
ISSN:2096-0956
年,卷(期):2024.43(5)