首页|银/导电共聚物复合涤纶织物的制备与表征

银/导电共聚物复合涤纶织物的制备与表征

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为优化涤纶织物的导电性能,拓展其在柔性电子器件领域的应用前景,以苯胺、吡咯为单体,纳米金属银为靶材,通过溶液聚合法和磁控溅射技术两步法制备了复合导电涤纶织物.研究了纳米金属膜在柔性纤维表面的生长模型,探讨了不同磁控溅射时间对复合织物的微观形貌、结晶性能、化学结构、电化学性能的影响规律.研究结果表明:通过磁控溅射的纳米金属银主要以"层状-岛状模式"在柔性织物基材表面生长;随着溅射时间增加,纳米金属银膜颗粒逐渐变得均匀,但时间过长时反而会变得粗糙,金属银膜在溅射时间为900 s时表现出较好的均匀性和致密性;磁控溅射金属银能够进一步改善复合织物的电化学性能,且在溅射时间为900 s、电流密度为1 mA/cm2时,织物的面积比电容达到峰值(67.1 mF/cm2),相比共聚物/涤纶织物(PANI-PPy/PET)增大了约3.3倍,因此在导电功能性纺织方面具有良好的应用前景.
Preparation and characterization of composite polyester fabric with silver and conductive copolymer
To enhance the conductivity of polyester fabric and broaden its application potential in the realm of flexible electronic devices,the conductive composite polyester fabric was prepared by solution polymerization and magnetron sputtering with aniline and pyrrole as monomers and nano-silver as the target material.The growth model of nano-metal film on the surface of flexible fiber was probed.Additionally,we examined how varing magnetron sputtering times impacted the microstructure,crystallization performance,chemical structure,and electrochemical performance of composite fabric.The results show that the nano silver grown by magnetron sputtering mainly grows on the surface of the flexible fabric substrate in a'layered-island mode'.As spattering time increases,the nano silver film particles become increasingly uniform;however,excessively long time results in roughness.The metallic silver film shows good uniformity and compactness when the sputtering time is 900 s.The electrochemical performance of the composite fabric can be further improved by magnetron sputtering silver metal.When the sputtering time is 900 s and the current density is 1 mA/cm2,the area specific capacitance of the fabric reaches a peak of 67.1 mF/cm,which is approximately 3.3 times higher than that of PANI-PPy/PET.These findings suggest promissing applications for functional conductive textiles.

silver nanoparticleconductive polymermagnetron sputteringconductive fabric

宋业诒、陈卓明、王艺琳、吴小燕、杨修美、梁静

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上海工程技术大学纺织服装学院,上海

纳米银 导电聚合物 磁控溅射 导电织物

国家级大学生创新训练项目上海市级大学生创新训练项目

202210856030CS2109001

2024

东华大学学报(自然科学版)
东华大学

东华大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.308
ISSN:1671-0444
年,卷(期):2024.50(1)
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