首页|抗污型CFC/TiO2光热织物的制备及其在海水淡化中的应用

抗污型CFC/TiO2光热织物的制备及其在海水淡化中的应用

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太阳能光热海水蒸发被认为是解决淡水危机的有效策略,但实际海水中存在油污和有机污染物,长期蒸发过程中污染物会黏附在光热膜表面,致使膜的蒸发性能下降.为实现海水的长期抗污型蒸发,制备兼具光热和光催化性能的碳纤维布(CFC)/TiO2织物.以CFC为衬底,通过水热法在其表面生长TiO2纳米棒阵列(TiO2纳米棒直径约为0.47μm、长度约为1.49 μm).结果显示:CFC/TiO2织物表现出超亲水和超疏油特性,同时具有宽光谱(280~2500 nm)光吸收性能(光吸收效率约为88%);在模拟太阳光激发下,CFC/TiO2还可光催化降解有机污染物,如在200 min内降解73%的盐酸四环素.将CFC/TiO2光热薄膜构筑成倾斜式海水蒸发器,在模拟阳光(光强为1 kW/m2)照射下,部分海水被蒸发,蒸发速率达1.68 kg/(m2·h),浓缩后的海水在织物底端滴落,长期蒸发不析盐.这种光热/光催化织物有望推动太阳能海水淡化走向实际应用.
Preparation of anti-fouling CFC/TiO2 photothermal fabric and its application in seawater desalination
Solar-driven seawater evaporation has been considered an effective strategy to solve the freshwater crisis,but natural seawater contains oil and organic contaminants that adhere easily to photothermal film during long-term evaporation,thus deteriorating the evaporation performance.To achieve long-term anti-fouling evaporation,we reported the construction of TiO2-coated carbon fiber cloth(CFC)with photothermal/photocatalytic features.TiO2 nanorods(diameter:~0.47 pm,length:~1.49 pm)were in-situ grown on CFC(as substrate material)surface by a hydrothermal method.CFC/TiO2 fabric shows super-hydrophilic and super-oleophobic performance,and it displays a strong photoabsorption in a wide range(280 to 2500 nm)with an absorption efficiency of 88%.CFC/TiO2 also exhibits photocatalytic activity toward organic pollutants under simulated sunlight,for instance,73%of tetracycline hydrochloride(TC)could be degraded within 200 min.Subsequently,CFC/TiO2 is hanging between the seawater tank and the empty tank to form a hanging-model evaporator.Under simulated sunlight(1 kW/m2)irradiation,part of the seawater can be evaporated at a high rate of 1.68 kg/(m2·h),while the concentrated seawater can drip from the fabric bottom,avoiding solid-salt crystallization during long-term evaporation.Therefore,the photothermal/photocatalytic fabric has the potential to promote solar desalination towards practical applications.

solar photothermal seawater evaporationanti-foulingcarbon fiber clothtitanium dioxidesalt-resistance

张晓涵、李小龙、朱波、张丽莎

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东华大学环境科学与工程学院,上海

东华大学国家环境保护纺织工业污染防治工程技术中心,上海

东华大学材料科学与工程学院,上海

太阳能光热海水蒸发 抗污 碳纤维布 二氧化钛 抗析盐

国家自然科学基金面上项目国家重点研发计划上海市自然科学基金

423760452022YFB380490021ZR1402500

2024

东华大学学报(自然科学版)
东华大学

东华大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.308
ISSN:1671-0444
年,卷(期):2024.50(4)