首页|高性能Sb2O4@C/CC锂离子电池复合电极

高性能Sb2O4@C/CC锂离子电池复合电极

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设计了以碳布(CC)为衬底,在其上生长金属有机框架的衍生物碳骨架(C),然后碳骨架内布局Sb2O4 纳米棒,即Sb2O4@C/CC复合电极.Sb2O4@C/CC复合电极具有优异的电化学性能,在0.1 A/g的电流密度下,其初始比容量高达1 616.1 mA·h/g,在100次循环后依然可逆,容量保持在1 161.5 mA·h/g,接近Sb2O4 的理论比容量(1 227 mA·h/g),优于已报道的Sb2O4 基复合材料.在1 A/g电流密度下,Sb2O4@C/CC电极的放电比容量高达837.2 mA·h/g,经过300次循环后,其容量仍保持在495.5 mA·h/g,接近初始容量的71.5%.在3 A/g的大电流密度下,Sb2O4@C/CC的可逆容量依然保持在311.3 mA·h/g.
High-performance Sb2O4@C/CC lithium-ion battery composite electrode
Herein,we report on designing derivative carbon skeleton(C)of metal organic framework grown on carbon cloth(CC)substrate and Sb2O4 nanorods inhabit C,Sb2O4@C/CC composite electrode.The Sb2O4@C/CC composite electrode exhibits excellent electrochemical performance,with an initial specific capacity of 1 616.1 mA·h/g at a current density of 0.1 A/g.The reversible capacity can still be maintained at 1 161.5 mA·h/g after 100 cycles,which is close to the theoretical specific capacity of Sb2O4(1 227 mA·h/g)and superior to reported Sb2O4 based composite material.At a current density of 1 A/g,the specific discharge capacity of Sb2O4@C/CC electrode is as high as 837.2 mA·h/g,and after 300 cycles,its capacity remains at 495.5 mA·h/g,which is close to 71.5%of the initial capacity.Even at a high current density of 3 A/g,the reversible capacity of the Sb2O4@C/CC electrode still remains at 311.3 mA·h/g.

lithium-ion batteryelectrochemical performancehydrothermal methodSb2O4

闫志宇、王春瑞

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东华大学 理学院,上海

锂离子电池 电化学性能 水热法 氧化锑

2024

东华大学学报(自然科学版)
东华大学

东华大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.308
ISSN:1671-0444
年,卷(期):2024.50(5)