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磷酸铁锂电池循环利用:从基础研究到产业化

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磷酸铁锂(LiFePO4)电池因其良好的循环性、高安全性、低成本在电动汽车和储能领域得到广泛应用,市场保有量的持续增加引发了对废旧LiFePO4电池循环利用的更多重视;然而LiFePO4自身的价值属性不突出、综合回收技术壁垒偏高,导致废旧LiFePO4电池的高值回收仍是LiFePO4电池循环利用的关键问题.本文总结了LiFePO4电池的退役路径和再生利用路径,从预处理、资源再生两方面梳理了LiFePO4正极废料再生利用的研究进展,得出了直接再生更具应用潜能但仍处于技术初步研究阶段、间接再生适合原料复杂性较高或需要高价值资源储备情况的基本判断.着眼LiFePO4正极废料再生利用产业化发展,识别出发展前提、发展关键、发展保障3个方面的产业化重要因素,展示了LiFePO4全组分短程再生利用技术及其万吨级生产线应用案例.进一步阐述了退役电池残能检测、智能化拆解预处理、正极废料直接再生等LiFePO4电池循环利用技术的发展趋势,原料来源及使用状况复杂、多种金属杂质精深脱除、正极材料更新换代等LiFePO4电池循环利用技术的应用挑战,提出了规范管理并顺畅回收渠道、加快关键技术攻关与应用转化、加强宣传和推广力度以提高市场接受度等发展建议,以畅通LiFePO4电池从基础研究到产业化的创新路径,促进LiFePO4电池循环利用及关联产业绿色发展.
Recycling of Lithium Iron Phosphate Batteries:From Fundamental Research to Industrialization
Lithium iron phosphate(LiFePO4)batteries are widely used in electric vehicles and energy storage applications owing to their excellent cycling stability,high safety,and low cost.The continuous increase in market holdings has drawn greater attention to the recycling of used LiFePO4 batteries.However,the inherent value attributes of LiFePO4 are not prominent and the comprehensive recycling technology faces significant barriers;therefore,high-value recovery of used LiFePO4 batteries remains a critical issue in the recycling of LiFePO4 batteries.This study summarizes the retirement and regeneration pathways of LiFePO4 batteries,reviewing the research progress in the regeneration of LiFePO4 cathode wastes from the perspectives of pretreatment and resource regeneration.It concludes that direct regeneration has greater application potentials but remains at an initial research stage while indirect regeneration is suitable for situations with complex raw materials or high-value resource reserves.Focusing on the industrial development of LiFePO4 cathode waste regeneration,this study identifies three key factors for industrialization:prerequisites for development,critical development aspects,and developmental guarantees.It showcases the short-range recycling technology for all components of LiFePO4,along with application cases of production lines at the scale of ten thousand tons.Furthermore,it elaborates on trends in the development of lithium-ion battery recycling technologies,including residual energy detection for retired batteries,intelligent disassembly pretreatment,and direct regeneration of cathode wastes.The challenges faced in the application of LiFePO4 battery recycling technologies include the complexity regarding raw material sources and usage conditions,the removal of various metal impurities,and the upgrading of cathode materials.Furthermore,the study proposes the following development recommendations:(1)establishing standardized management and efficient recovery channels,(2)accelerating breakthroughs in key technologies and their application conversion,and(3)enhancing publicity and promotion efforts to improve market acceptance.These strategies aim to streamline the innovation pathway of LiFePO4 batteries from fundamental research to industrialization,promoting LiFePO4 battery recycling and the green development of related industries.

lithium iron phosphate batteriesrecyclepretreatmentregenerationindustrialization

王玥、郑晓洪、阮丁山、郑诗礼、曹宏斌、李长东、孙峙

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中国科学院过程工程研究所,北京 100190

中国科学院化学化工科学数据中心,北京 100190

广东邦普循环科技有限公司,广东佛山 528137

磷酸铁锂电池 回收 预处理 循环再生 产业化

中国科学院战略性先导科技专项国家自然科学基金项目浙江省科技计划项目

XDA0430105523002382022C03074

2024

中国工程科学
中国工程院,高等教育出版社有限公司

中国工程科学

CSTPCD北大核心
影响因子:0.737
ISSN:1009-1742
年,卷(期):2024.26(5)
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