Abstract
A single-sheet bipolar membrane was synthe-sized via photografting polymerization of an acrylic acid cation exchange layer onto the surface of a commercial homogeneous anion exchange membrane with benzophenone (BP) as the main initiator, diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide (TPO) and 2-hydroxy-2-methyl-1-phenyl-1-propanone (1173) as co-initiators and divinylbenzene (DVB) or neopentylene glycol diacrylate (NPGDA) as crosslinking agent. It was found that when benzophenone was used as single initiator and the crosslink agent is absent, the grafting degree (Dg) increases with the prolongation of irradia-tion time. The grafting degree reaches a maximum at 60 seconds reaction time when the crosslinking agent is added, and the grafting degree is higher when using NPGDA instead of DVB as crosslinking agent. The grafting degree increases as the composite initiator system is used. When polymerization was initiated by BP and TPO, and the dosage of NPGDA was 2.5% mol concentration of monomer, the grafting degree reaches 30.1%.
基金项目
北京市自然科学基金(KM200410011004)
NETL
NSTL
万方数据