中国化学前沿2008,Vol.3Issue(1) :94-98.

Accurate measurement of neodymium isotopic composition using Neptune MC-ICP-MS

Yueheng YANG Hongfu ZHANG Liewen XIE Fuyuan WU
中国化学前沿2008,Vol.3Issue(1) :94-98.

Accurate measurement of neodymium isotopic composition using Neptune MC-ICP-MS

Yueheng YANG 1Hongfu ZHANG 2Liewen XIE 2Fuyuan WU2
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作者信息

  • 1. State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;Graduate University of Chinese Academy of Sciences, Beijing 100039, China
  • 2. State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
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Abstract

This paper reports the measurement of the Neodymium isotopic composition by Neptune Multiple Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) over the last two years. Although there is concomitant Cerium in the chemical separation process, this has no significant influence on the Neodymium analysis. As for the sample containing small amounts of Samarium (Sm/Nd<0.04), direct calibration for isobaric interference and mass discrimina-tion by the exponential law can be obtained by assuming that Samarium mass discrimination is the same as that of Neodymium. Geological samples after traditional chemi-cal separation were measured by Neptune MC-ICP-MS and Thermal Ionization Mass Spectrometry (TIMS) respectively. The results show that Neptune MC-ICP-MS can measure Neodymium isotopic composition as precisely the TIMS does and is even more effective and less time-consuming than the TIMS Method.

Key words

MC-ICP-MS/neodymium isotopic composi-tion/cerium and Samarium isobaric correction

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基金项目

国家自然科学基金(40534022)

出版年

2008
中国化学前沿
高等教育出版社

中国化学前沿

ISSN:1673-3495
被引量2
参考文献量4
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