Synthesis-characterization and photosensitivity of tetrakis-α-(2-methyl-8-quinolinoxy) metallophthalocyanines

Jinping XUE ¹Hong LIU ²Changan FAN ³Huming HONG ⁴Naisheng CHEN ²Jinling HUANG²

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作者信息

1. Institute of Functional Materials,College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou 350002,ChinaHuming HONGLaboratory of Physics and Chemistry,Taigu Aeroengineering Ltd.,Xiamen 361006,ChinaChangan FANFujian Sanming Jianning Fire Compa
2. Institute of Functional Materials,College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou 350002,China
3. Fujian Sanming Jianning Fire Company,Sanming 354500,China
4. Laboratory of Physics and Chemistry,Taigu Aeroengineering Ltd.,Xiamen 361006,China
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Abstract

Four amphipathic cobalt(Ⅱ),nickel(Ⅱ),copper (Ⅱ),and zinc(Ⅱ) coordination compounds of tetrakis,α,(2,methyl,8,quinolinoxy)phthalocyanine are synthesized using "DBU catalytic method". The titled complexes are characterized by elemental analysis,mass spectra,UV,Vis,and IR spectra. In addition,the rates of photogenerated singlet oxygen and the rate constants of photodynamic oxidation of amino,acid substrate by the complexes are measured under the optical excitation at 670 nm,and the relations between their structures and their photosensitivities are discussed.

Key words

2-methyl-8-quinolinoxy/metallophthalocaynine/synthesis-characterization/photosensitivity

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基金项目

Fujian Provincial Department of Science & Technology(20031018)

Key Project of Fujian Provincial Department of Science & Technology(2006Y0020)

出版年

2008

中国化学前沿

高等教育出版社

中国化学前沿

ISSN：1673-3495

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