中国化学前沿2008,Vol.3Issue(3) :320-324.

Synthesis of silica adsorbent and its selective separation for flavone

Yuqing ZHANG Yahui ZHANG Zhen QIN Zhenrong MA
中国化学前沿2008,Vol.3Issue(3) :320-324.

Synthesis of silica adsorbent and its selective separation for flavone

Yuqing ZHANG 1Yahui ZHANG 1Zhen QIN 1Zhenrong MA1
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作者信息

  • 1. School of Chemical Engineering and Technology, TianjinUniversity, Tianjin300072, P. R. China
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Abstract

One kind of built,in silica adsorbent, which has high adsorption selectivity to rutin, was synthesized using molecular imprinting technology by the following steps:synthesis of precursor from the reaction between water soluble rutin (as template molecule) and the functional monomer chloropropyltriethoxysilane, co,hydrolysis of the precursor and tetraethoxysilane (TEOS), sol,gel aging process, and removal of template molecules. The results of adsorption experiment show that this adsorbent has a high adsorption capacity for rutin, and good adsorptionselectivity towards rutin even under the interference of a flavone with a similar structure. TEM photos suggest that nanocaves corresponding to rutin were formed inside the adsorbent while FTIR spectra indicate that new bond was generated during the recognition process.

Key words

silica adsorbent/molecular imprinted technology (MIT), selective adsorption/rutin

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出版年

2008
中国化学前沿
高等教育出版社

中国化学前沿

ISSN:1673-3495
参考文献量4
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