Chemiluminescence system of Ce(IV)-RhB-bismerthiazol
Shuhua HE 1Deyong HE 2Zhujun ZHANG3
作者信息
- 1. Department of Chemistry,Yangtze Normal University,Chongqing 408003,China
- 2. College of Chemistry and Chemical Engineering,Jinggangshan University,Ji'an 343009,China
- 3. College of Chemistry and Chemical Engineering,Southwest University,Chongqing 400715,China
- 折叠
Abstract
A novel chemiluminescence system for the determination of bismerthiazol is first described in this paper. It is based on the chemiluminescence reaction of bismerthiazol and Ce(Ⅳ) in nitric acid solution. The emis-sion intensity could be enhanced greatly by Rhodamine B. The chemiluminescence intensity was proportional to bis-merthiazol concentration over the range 30-1000 μg/L. The detection limit was 12 μg/L (3σ) and the relative standard deviation is 2.4% for 500 μg/L of bismerthiazol (n = 11). The proposed method was successfully applied to the determination of bismerthiazol in water and in rice. The recovery was 96.4%-104.1%.
Key words
bismerthiazol/flow injection analysis/rhoda-min B/chemiluminescence引用本文复制引用
出版年
2008
NETL
NSTL
万方数据