Synthesis and characterization of polyarylene sulfide sulfone/ketone amide

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外文摘要：High-molecular-weight polyarylene sulfide sulfone amide (PASSA) and polyarylene sulfide ketone amide (PASKA) were synthesized from diamine mono-mers containing sulfone or ketone group by a low temperature solution polycondensation reaction in anhy-drous N-methylpyrrolidone (NMP). The structures of the monomers and corresponding polymers were identified by IR-spectra and UV spectra. The maximum intrinsic viscosities of the polymers were 0.72dL/g in NMP (PASSA) and 0.62 dL/g in H2SO4 (PASKA) at 30±0.1℃,respectively. The polymers possess excellent thermalproperties with the glass transition temperature (Tg) for PASSA and PASKA are 274.9℃ and 195.2℃, respec-tively. The initial degradation temperatures (T i) for PASSA and PASKA are 461.55℃ and 467.08℃, respectively,which suggests that PASSA and PASKA are excellent heat-resistant materials. The dissolvability experiments show that PASSA and PASKA are also corrosion resistance materials.

外文关键词：

polyarylene sulfide sulfone, polyarylene sul-fide amine, polyarylene sulfide sulfone amide, polyarylene sulfide ketone amide, 4,4'-bis(4-aminothio phenyl)diphenyl sulfone, 4,4'-bis(4,-aminothiophenyl) diphenyl ketone

作者：

Chengkun CHEN、Chunli LIU、Gang ZHANG、Jie YANG、Shengru LONG

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作者单位：

Institute of Materials and Technology, Sichuan University, Chengdu 610064, China

College of Chemistry, Sichnan University, Chengdu 610065, China

State Key Laboratory of Polymer Materials and Engineering, Sichuan University, Chengdu 610065, China

基金：

国家高技术研究发展计划(863计划)

项目编号：

2001AA33402021

出版年：

2009

DOI：

10.1007/s11458-009-0015-x

中国化学前沿

高等教育出版社

中国化学前沿

ISSN：1673-3495

年,卷(期)：2009.4(1)

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