中国化学前沿2011，Vol.6Issue(1) ：21-30.DOI:10.1007/s11458-011-0225-x

Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF-5/KI and MOF-5/KI/K2CO3

Jinliang SONG Binbin ZHANG Tao JIANG Guanying YANG Buxing HAN
中国化学前沿2011，Vol.6Issue(1) ：21-30.DOI:10.1007/s11458-011-0225-x
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Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF-5/KI and MOF-5/KI/K2CO3

Jinliang SONG 1Binbin ZHANG 1Tao JIANG 1Guanying YANG 1Buxing HAN1
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作者信息

  • 1. Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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Abstract

The synthesis of cyclic carbonates or dimethyl carbo-nate (DMC) using CO2 as a building block is a very interesting topic. In this work, we found that the metal-organic framework-5 (MOF-5)/KI was an active and a selective catalytic system for the synthesis of cyclic carbonates from CO2 and epoxides, and MOF-5/KI/K2CO2was efficient for the preparation of DMC from CO2, propylene, and methanol by a sequential route.The impacts of temperature, pressure, and reaction time length on the reactions were investigated, and the mechanism of the reactions is proposed on the basis of the experimental results.

Key words

carbon dioxide/cyclic carbonates/dimethyl carbonate (DMC)/metal-organic framework-5 (MOF-5)/sequential route/propylene oxide

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基金项目

国家自然科学基金(21003133)

国家自然科学基金(20932002)

科技部资助项目(2009CB930802)

中国科学院资助项目(KJCX2.YW.H16)

出版年

2011
中国化学前沿
高等教育出版社

中国化学前沿

ISSN：1673-3495
参考文献量48
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