首页|Investigation of the interaction of ethyl acetoacetate with nano alumina particle as Lewis acid in acetonitrile solvent

Investigation of the interaction of ethyl acetoacetate with nano alumina particle as Lewis acid in acetonitrile solvent

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The enol form of ethyl acetoacetate (EAA) displays interesting spectroscopic characteristics; this form of ethyl acetylacetate is very important in condensation reaction.In this investigation,we have studied the interactions and the complex formation constants (Kf) with nano alumina (10-20 nm) particle and alumina (mesh 135) compounds as Lewis acids in the acetonitrile solvent using absorption spectroscopy and related calculations.Furthermore,in this study we calculated the thermodynamic parameters of this reaction.The trend of reactivity of the ethyl acetoacetate (EAA)complexes toward the above Lewis acids,based on the solvent as follows:nano alumina compound> alumina compound.

complex formation constantethyl acetoacetatenano aluminaaluminathermodynamic

Asadollah FARHADI、Mohammad AliTAKASSI、Mandana DAYER

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Faculty of Science, Petroleum University of Technology, Ahwaz 61981-44471, Iran

Departmcnt of Chemistry, Science and Research Branch, Islamic Azad University, Khouzestan, Iran

2011

中国化学前沿
高等教育出版社

中国化学前沿

ISSN:1673-3495
年,卷(期):2011.6(3)
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