中国化学前沿2011,Vol.6Issue(4) :310-331.DOI:10.1007/sl1458-011-0251-8

Self-consistent field theory and its applications in polymer systems

Dadong YAN Tongchuan SUO Xinghua ZHANG Xingkun MAN Bing MIAO
中国化学前沿2011,Vol.6Issue(4) :310-331.DOI:10.1007/sl1458-011-0251-8

Self-consistent field theory and its applications in polymer systems

Dadong YAN 1Tongchuan SUO 2Xinghua ZHANG 3Xingkun MAN 2Bing MIAO2
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作者信息

  • 1. Department of Physics, Beijing Normal University, Beijing 100875,China
  • 2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190,China
  • 3. Department of Physics, Beijing Normal University, Beijing 100875,China;Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190,China
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Abstract

This review article addresses the widely used selfconsistent field theory (SCFT) in interacting polymer systems.The theoretical framework and numerical method of solving the self-consistent equations are presented.In this paper,different structures of polymer can be considered,such as homopolymer,block copolymer,polydisperse polymer and charged polymer.Several systems,micro/macro phase separation,interface,self-assembly,are presented as examples to demonstrate its applications in details.Besides,the fluctuation effects are considered.The first order is Gaussian fluctuation theory,which can be used to determine the stability of the mean-field solution and predict the kinetics of unstable structure.The derivation and applications of Gaussian fluctuation theory are presented as well.

Key words

self-consistent field theory (SCFT)/Gaussian fluctuation theory/self-assembly/adsorption/depletion/polyelectrolyte/confinement

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出版年

2011
中国化学前沿
高等教育出版社

中国化学前沿

ISSN:1673-3495
被引量1
参考文献量33
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