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Self-consistent field theory and its applications in polymer systems

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This review article addresses the widely used selfconsistent field theory (SCFT) in interacting polymer systems.The theoretical framework and numerical method of solving the self-consistent equations are presented.In this paper,different structures of polymer can be considered,such as homopolymer,block copolymer,polydisperse polymer and charged polymer.Several systems,micro/macro phase separation,interface,self-assembly,are presented as examples to demonstrate its applications in details.Besides,the fluctuation effects are considered.The first order is Gaussian fluctuation theory,which can be used to determine the stability of the mean-field solution and predict the kinetics of unstable structure.The derivation and applications of Gaussian fluctuation theory are presented as well.

self-consistent field theory (SCFT)Gaussian fluctuation theoryself-assemblyadsorptiondepletionpolyelectrolyteconfinement

Dadong YAN、Tongchuan SUO、Xinghua ZHANG、Xingkun MAN、Bing MIAO

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Department of Physics, Beijing Normal University, Beijing 100875,China

Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190,China

2011

中国化学前沿
高等教育出版社

中国化学前沿

ISSN:1673-3495
年,卷(期):2011.6(4)
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