首页|Self-consistent field theory and its applications in polymer systems
Self-consistent field theory and its applications in polymer systems
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This review article addresses the widely used selfconsistent field theory (SCFT) in interacting polymer systems.The theoretical framework and numerical method of solving the self-consistent equations are presented.In this paper,different structures of polymer can be considered,such as homopolymer,block copolymer,polydisperse polymer and charged polymer.Several systems,micro/macro phase separation,interface,self-assembly,are presented as examples to demonstrate its applications in details.Besides,the fluctuation effects are considered.The first order is Gaussian fluctuation theory,which can be used to determine the stability of the mean-field solution and predict the kinetics of unstable structure.The derivation and applications of Gaussian fluctuation theory are presented as well.
self-consistent field theory (SCFT)Gaussian fluctuation theoryself-assemblyadsorptiondepletionpolyelectrolyteconfinement