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核电厂蒸汽发生器湿保养方案优化分析研究

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核电厂在停堆大修期间对蒸汽发生器(SG)二次侧实施保养,主要采用干保养和湿保养两种方案,以降低机组在停堆期间及后续机组启动和功率运行期间SG二次侧内部构件的腐蚀,其中湿保养主要控制保养液的pH、联氨浓度和腐蚀性杂质离子.国外针对湿保养条件(覆盖气体、pH、联氨等)对材料的腐蚀影响开展了大量的试验及研究,而目前国内相应研究报道较少.核电厂SG湿保养方案中指标制定规则不一、规范要求差异较大且不具体,存在不利于现场执行、联氨浓度偏高或pH偏低等情况.本文对材料腐蚀试验结果进行了分析,表明氮气覆盖、pH>10、联氨>75 mg/kg均有利于缓解碳钢腐蚀,并结合核电厂保养实际,提出了 SG湿保养优化方案,为核电厂优化SG湿保养方案提供支撑.
Research and Analysis of Optimization of Program for SG Wet Layup during Shutdown in Nuclear Power Plants
In order to mitigate corrosion of internal materials during outage and subsequent power operation,steam generator(SG)is put into dry or wet layup.During wet layup,the pH,hydrazine and the corrosive impurity are the mainly controlled.Large numbers of tests and studies on effect of wet layup conditions,such as pH and hydrazine,on materials corrosion were carried out in foreign plants and institutions.However,at present,there are few systematic researches on wet layup specification in domestic plants.The rules of specification definition are different and the specification requirements are different and not specific for SG wet layup.Therefore,it is not conducive to implement and cause higher hydrazine concentration or lower pH.In this paper,corrosion test of materials was analyzed and it is concluded that wet layup under N2 blanket,pH>10 or N2H4>75 mg/kg are all helpful for mitigating the corrosion of carbon steel.Then,optimization of wet layup strategy was proposed accordingly with considering plant conditions.It could provide support for plants to optimize SG wet layup strategy.

SGwet layuppHhydrazine

王森、秦建华、游兆金、孙金娜、彭冰

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中核核电运行管理有限公司,浙江 海盐 314300

蒸汽发生器 湿保养 pH 联氨

2024

中国核电
中国原子能出版社

中国核电

影响因子:0.296
ISSN:1674-1617
年,卷(期):2024.17(5)