首页|Design of Support Effect in the Catalytic Application of Ligand-Protect Gold Clusters

Design of Support Effect in the Catalytic Application of Ligand-Protect Gold Clusters

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Ligand-protected gold(Aun)clusters sometimes need the removal of organic ligands to expose more active sites and reduce steric hindrance in catalytic reactions,and large amount of organic and inorganic materials usually need to be employed as supports to anchor Aun clusters through different interaction mechanisms.Whereas,less comprehensive summaries have been provided about the crucial contribution of various supports to the catalytic performance of the supported Aun clusters.Herein,this review firstly summarizes synthesis methods(e.g.,impregnation and encapsulation processes)for the supported Aun cluster catalysts,and then mainly points out specific contributions of support effect in a great diversity of catalytic reactions,as well as deep interaction mech-anisms.Besides,opportunities and challenging issues will be stated towards supported Aun clusters,in terms of improving catalytic performance and structural stability of Aun clusters in the demand of catalysis.

Gold clustersSynthesisSupport effectCatalytic performanceInteraction

Shuohao Li、Shenguang Fu、Yuqing Gong、Nuojie Wu、Lei Wang、Liang Wang

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School of Safety Engineering,China University of Mining and Technology,Xuzhou,Jiangsu 221116,China

Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization,China University of Mining and Technology,Xuzhou,Jiangsu 221008,China

School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou,Jiangsu 225009

国家自然科学基金国家自然科学基金Jiangsu Key Laboratory of Coalbased Greenhouse Gas Control and Utilization中央高校基本科研业务费专项

5220425522301267PCSX202201JY220007

2024

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子:0.848
ISSN:1001-604X
年,卷(期):2024.42(1)
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