首页|Carbon Monoxide as C1 Building Block in Fine Chemical Synthesis

Carbon Monoxide as C1 Building Block in Fine Chemical Synthesis

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Carbon monoxide(CO)has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis,es-pecially in the fine chemicals industry,due to the development of efficient and selective catalysts for its activation.In this review,we present a comprehensive critical analysis of the last 10 years literature on the use of CO as a renewable feedstock for fine chemicals production.The review is organized by type of catalytic reaction,namely alkene and alkyne carbonylation,hydroformylation,car-bonylation of aryl halides,carbonylative cross-coupling and C-H carbonylation.Notable examples of the synthesis of relevant building blocks and/or known pharmaceuticals are highlighted.Emphasis is placed on examples of utilizing CO as the C1 building block in one or more catalytic steps.The catalyst used and the reaction conditions are consistently presented throughout all of the examples.

Carbon monoxideFine chemicalsCarbonylationHydroformylationC-H functionalization

Rui M.B.Carrilho、Mário J.F.Calvete、Gábor Mikle、László Kollár、Mariette M.Pereira

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University of Coimbra,Coimbra Chemistry Centre,Department of Chemistry,Rua Larga,3004-535 Coimbra,Portugal

Department of General and Inorganic Chemistry and ELKH-PTE Research Group for Selective Chemical Syntheses,University of Pécs,Ifjúság útja 6,H-7624 Pécs,Hungary

Portuguese Agency for Scientific Research(FCT)COMPETE2020-UE,for funding through projects to Coimbra Chemistry Centre(CQC)COMPETE2020-UE,for funding through projects to Coimbra Chemistry Centre(CQC)COMPETE2020-UE,for funding through projects to Coimbra Chemistry Centre(CQC)COMPETE2020-UE,for funding through projects to Coimbra Chemistry Centre(CQC)COMPETE2020-UE,for funding through projects to Coimbra Chemistry Centre(CQC)MTA Distinguished Guest Scientist Fellowship(2023)NKFIH for funding through project

UIDB/00070/2020UIDP/00070/2020UIDB/00313/2020UIDP/00313/2020UIDB/00285/2020TKP2021-EGA-17

2024

10.1002/cjoc.202300384

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子：0.848
ISSN：1001-604X
年,卷(期)：2024.42(2)
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