Decarboxylative Amination with Nitroarenes via Synergistic Catalysis

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外文摘要：In this paper,we have developed a decarboxylative amination of carboxylic acids with nitroarenes for the synthesis of secondary amines.The protocol is performed at mild conditions without the use of noble metals as catalysts.A wide range of structurally diverse secondary amines could be obtained in good yields(up to 94％)with good functional group tolerance.This transformation shows good to excellent selectivity,avoiding the generation of over alkylated byproducts.

外文关键词：

NitroarenesAminesSynergistic catalysisCarboxylic acidsRadical alkylationAminationPhotocatalysisSteric hindrance

作者：

Meiling Ding、Sitian Zhou、Shunruo Yao、Chengjian Zhu、Weipeng Li、Jin Xie

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作者单位：

State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,Chemistry and Biomedicine Innovation Center(ChemBIC),School of Chemistry and Chemical Engineering,Nanjing University,Nanjing,Jiangsu 210023,China

Green Catalysis Center,and College of Chemistry,Zhengzhou University,Zhengzhou,Henan 450001,China

基金：

国家重点研发计划国家重点研发计划国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金中央高校基本科研业务费专项中央高校基本科研业务费专项中央高校基本科研业务费专项

项目编号：

2022YFA15032002021YFC21019012212210322101130220011172197110822271144020514380304020514380252020514380272

出版年：

2024

DOI：

10.1002/cjoc.202300493

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(4)

参考文献量53