首页|Ru(Ⅱ)-Catalyzed ortho C—H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate
Ru(Ⅱ)-Catalyzed ortho C—H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate
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A Ru(Ⅱ)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been developed.This reaction is an effective pathway for synthesizing 7-azaindole derivatives with a wide scope of substrates and high yields.In addition,the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates,highlighting the practicality of this strategy for synthesis.
Jing Zhang、Quan-Jian Luo、Han-Chi Wang、Jin-Heng Li、Bo Sun
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State Key Laboratory Base of Eco-Chemical Engineering,College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao,Shandong 266042,China
State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou,Gansu 730000,China
School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang,Henan 453007,China
Natural Science Foundation of Shandong ProvinceScientific Research Foundation of Qingdao University of Science & Technology
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