首页|Access to Versatile Functionalized Cu(Ⅲ)Complexes Enabled by Direct Transmetalation to Well-Defined Copper(Ⅲ)Fluoride Complex Me4N+[Cu(CF3)3F]-
Access to Versatile Functionalized Cu(Ⅲ)Complexes Enabled by Direct Transmetalation to Well-Defined Copper(Ⅲ)Fluoride Complex Me4N+[Cu(CF3)3F]-
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The invention of a well-defined Cu(Ⅲ)fluoride complex Me4N+[Cu(CF3)3(F)]-1 enabled to access a versatile of functionalized Cu(Ⅲ)complexes[Me4N]+[Cu(X)(CF3)3]-(X=C6F5,C6F5C≡C,CN,Cl,N3,tBuOO,SCN,OAc,SAr),many of them for the first time.The availability of these complexes allowed us to evaluate the trans-influence order of ligand in Cu(Ⅲ)complexes:Bn＞CF3-＞C6F5-＞N3-＞py～CH3-～C6F5C≡C＞NO2PhO-～tBuOO～CH3COO-＞F-.
Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Chinese Academy of Sciences,345 Lingling Lu,Shanghai 200032,China
National Key Research and Development Program of ChinaNational Natural Science Foundation of China
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