首页|Photoinduced Dehalocyclization to Access Oxindoles Using Formate as a Reductant

Photoinduced Dehalocyclization to Access Oxindoles Using Formate as a Reductant

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Herein,we report an efficient and practical protocol for the photoinduced dehalocyclization of ortho-halophenylacrylamides with formate by the engagement of a CO2 radical anion to access substituted oxindoles.This method proceeds smoothly under mild conditions and exhibits a wide range of substrate as well as remarkable functional group compatibility.

FormateCO2 Radical ionsOxindolePhotocatalystsCyclizationOrganohalides

Wei Ge、Jia-Xin Wang、Ming-Chen Fu、Yao Fu

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Hefei National Research Center for Physical Sciences at the Microscale,iChEM,CAS Key Laboratory of Urban Pollutant Conversion,Anhui Province Key Laboratory of Biomass Clean Energy,University of Science and Technology of Chino,Hefei,Anhui 230026,China

Anhui Province Key Laboratory of Value-Added Catalytic Conversion and Reaction Engineering,Hefei University of Technology,Hefei,Anhui 230009,China

National Natural Science Foundation of China

22293011

2024

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子:0.848
ISSN:1001-604X
年,卷(期):2024.42(11)