首页|Pd-Catalyzed Highly Regioselective Hydroesterification of Terminal Alkyl Olefins with Formates
Pd-Catalyzed Highly Regioselective Hydroesterification of Terminal Alkyl Olefins with Formates
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
万方数据
维普
A Pd-catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described.A wide variety of linear car-boxylic esters bearing various functional groups can be obtained in good yields with high regioselectivities under mild reaction condi-tions by using 1,2-DTBPMB or(p-F-Ph)3P as ligand.The reaction process is operationally simple and requires no handling of toxic CO or strong acid.The resulting aryl esters can be readily converted to other carboxylic acid derivatives.
Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology,School of Petrochemical Engineering,Institute of Natural and Synthetic Organic Chemistry,Changzhou University,Changzhou,Jiangsu 213164,China
National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaChangzhou University
万方数据
维普
