Recent Advances in Photochemical/Electrochemical Carboxyla-tion of Olefins with CO2

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外文摘要：CO2 is an abundant,nontoxic,and renewable C1 feedstock in synthetic chemistry.Direct carboxylation of readily available olefins in-corporating CO2 is regarded as a promising strategy to access high value-added carboxylic acids as well as CO2 fixation.However,due to the thermodynamic stability and kinetic inertness of CO2 and the difficulty in controlling the regioselectivity,the carboxylation of olefins with CO2 still remains challenging.Radical-type functionalization with olefins represented a powerful protocol and enabled the development of novel transformations in this realm.More recently,the advance of new technology,such as photoredox catalysis and the renaissance of electrochemistry in organic synthesis,offered access to unique chemical reactivities of radical precursors and pro-vided new solutions to the functionalization of olefins.This review presents the recent advances in the radical-type carboxylation of olefins,which has mainly been achieved through photocatalysis and electrocatalysis in the last decade.In this article,we provide a comprehensive introduction of the progress,summarize the advantages and limitations of current research,and discuss the potential outlook for further development.

外文关键词：

CO2CarboxylationOlefinsPhotocatalysisElectrocatalysisRadicalReductionDifunctionalization

作者：

Qian Wang、Yanwei Wang、Min Liu、Ganghui Chu、Youai Qiu

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作者单位：

Xinjiang Laboratory of Native Medicinal and Edible Plant Resources Chemistry,College of Chemistry and Environmental Science,Kashi University,Kashi,Xinjiang 844000,China

State Key Laboratory and Institute of Elemento-Organic Chemistry,Frontiers Science Center for New Organic Matter,College of Chemistry,Nankai University,94 Weijin Road,Tianjin 300071,China

出版年：

2024

DOI：

10.1002/cjoc.202400008

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(18)